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Synthesis and Optical Properties of Single Crystal WO3 Nanoplates with Nano-Pits

  • ZHU Qing-Jun ,
  • YU Jian-Chang ,
  • HUANG Qing-Ming ,
  • ZHANG Xin-Qi
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  • (College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108)

Received date: 2011-04-26

  Revised date: 2011-07-13

  Online published: 2011-08-24

Abstract

Using tungstate (Na2WO4•2H2O) and mesoporous silica dioxide (SBA-15) as tungsten raw material and hard template respectively, tungsten oxide nanoplates with nano-pits were successfully synthesized in the acidic condition by a modified dipping-reduction method. The composition, morphology and optical properties of as-prepared products were characterized by X-ray diffraction (XRD), energy dispersive X-ray (EDX), scanning electron microscope (SEM), high resolution transmission electron microscopy (HRTEM) and ultraviolet-visible transmission spectrum (UV-Vis). Results showed that the products were single crystal tungsten oxide nanoplates with nano-pits which had higher transmission rate in the near UV-visible region. Furthermore, The WO3 thin films changed from the monoclinic to monoclinic phase and orthogonal phase with the increase of sintered temperature, and the UV-visible light transmittance increased with sintered temperature of WO3 thin film.

Cite this article

ZHU Qing-Jun , YU Jian-Chang , HUANG Qing-Ming , ZHANG Xin-Qi . Synthesis and Optical Properties of Single Crystal WO3 Nanoplates with Nano-Pits[J]. Acta Chimica Sinica, 2011 , 69(24) : 2955 -2958 . DOI: 10.6023/A1104263

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