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Acta Chimica Sinica >

2012 , Vol. 70 >Issue 01: 35 - 38

DOI: https://doi.org/10.6023/A1105163

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Non-noble Metallic Fe Catalyst Systems for the Reductive Carbonylation of Nitrobenzene

  • ZHANG Jun ,
  • LI Yun-Ping ,
  • ZHAO Bang-Tun
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  • College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022

Received date: 2011-05-16

  Revised date: 2011-09-14

  Online published: 2012-02-25

Supported by

Project was supported by the National Natural Science Foundation of China(No.20872058).

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Abstract

A silica-supported chitosan-iron complex SiO2-CS-FeCl3 has a good conversion for reductive carbonylation of nitrobenzene.The high activity and selectivity of the catalyst have been achieved by the synergic effect of Fe-Ni bimetallic system and the effect of polymer protection.

Key words： reductive carbonylation; carbamate; nitrobenzene; chitosan

Cite this article

ZHANG Jun , LI Yun-Ping , ZHAO Bang-Tun . Non-noble Metallic Fe Catalyst Systems for the Reductive Carbonylation of Nitrobenzene[J]. Acta Chimica Sinica, 2012 , 70(01) : 35 -38 . DOI: 10.6023/A1105163

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