SIOC 中文
ACS
Adv search

Acta Chimica Sinica >

2012 , Vol. 70 >Issue 03: 247 - 253

DOI: https://doi.org/10.6023/A1108224

Full Papers

Preparation and Luminescent Properties of Series of Strontium Metaborate Light-emitting Materials

  • HUANG Hong-Sheng ,
  • LIU Zhi-Hong
Expand
  • Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062

Received date: 2011-08-22

  Revised date: 2011-11-12

  Online published: 2011-11-21

Supported by

Project supported by the National Natural Science Foundation of China (No. 20871078), and the Natural Science Foundation of Shaanxi Province of China(No. SJ08B01).

Fold

Abstract

The SrB2O4·4H2O and SrB2O4·4H2O:Eu3+ light-emitting materials have been synthesized by liquid coprecipitation method, and SrB2O4 and SrB2O4:Eu3+ have been synthesized by calcination precursor method. All the as-prepared products were characterized by the XRD, EDS and SEM, respectively. Their luminescent properties were investigated by fluorescence spectroscopy, and the influences of reaction time and the doping concentration of Eu3+ on the emission intensities have also been investigated. The results show that the matrixes of SrB2O4·4H2O and SrB2O4 have stronger luminescence in the UV region, and SrB2O4·4H2O:Eu3+ and SrB2O4:Eu3+ samples have the strongest emission peaks near 613 nm. By adjusting the reaction time and increasing the amount of doping, the quenching effect of structural water on the luminescence can be overcome, which improves the luminescence of SrB2O4·4H2O:Eu3+ with higher redorange ratio. It shows that SrB2O4·4H2O is a new good hydrated borate matrix for light-emitting materials.

Key words： strontium metaborate; hydrated borate; preparation; luminescent property

Cite this article

HUANG Hong-Sheng , LIU Zhi-Hong . Preparation and Luminescent Properties of Series of Strontium Metaborate Light-emitting Materials[J]. Acta Chimica Sinica, 2012 , 70(03) : 247 -253 . DOI: 10.6023/A1108224

References

1 Kim, J. B.; Lee, K. S.; Kim, J. N. Mater. Lett. 1997, 31, 93.

2 Pan, F.; Shen, G. Q.; Wang, R.; Wang, X. Q.; Shen, D. Z.; Chen, J. S. J. Cryst. Growth 2002, 241, 108.

3 Leger, J. M.; Chateau, C.; Lacam, A. J. Appl. Phys. 1990, 68, 2351.

4 Su, Q.; Liang, H. B.; Hu, T. D. J. Alloys Compd. 2002, 344, 132.

5 Li, P. L.; Wang, Z. J.; Yang, Z. P. Mater. Res. Bull. 2009, 44, 2068.

6 Wang, H. Y.; Wang, R. J.; Zhang, M.; Li, Y. D. J. Inorg. Mater 2004, 19, 1367 (in Chinese). (王海英, 王如骥, 张明, 李亚栋, 无机材料学报, 2004, 19, 1367.)

7 Machida, K. I.; Adachi, G. Y.; Shiokawa, J.; Shimada, M.; Koizumi, M. K. Inorg. Chem. 1980, 19, 983.

8 Dotsenko, V. P.; Berezovskaya, I. V.; Efryushina, N. P. Radiat. Meas. 2007, 42, 803.

9 Xu, W.; Su, W. H.; Cui, S. J.; Wu, D. M. Chin. J. High. Press. Phys. 1988, 2, 237 (in Chinese). (许伟, 苏文辉, 崔硕景, 吴代鸣, 高压物理学报, 1988, 2, 237.)

10 Stefani, R.; Maia, A. D.; Teotonio, E. E. S. J. Solid State Chem. 2006, 179, 1086.

11 Zhang, L. J.; Ye, X. C. Chin. J. Lumin. 2009, 30, 184 (in Chinese). (张林进, 叶旭初, 发光学报, 2009, 30, 184.)

12 Zeng, Q. H.; Pei, Z. W.; Wang, S. B.; Su, Q. J. Alloys Compd. 1998, 275～277, 238.

13 Zeng, Q. H.; Pei, Z. W.; Wang, S. B.; Su, Q. Spectrosc. Lett. 1999, 32, 895

14 Yang, J.; Zhang, C. M.; Wang, L. L. J. Solid State Chem. 2008, 181, 2672.

15 Xie, X. D.; Zheng, M. P.; Liu, L. B. Borate Minerals, Science Press, Beijing, 1965, pp. 30～34 (in Chinese). (谢先德, 郑绵平, 刘来保, 硼酸盐矿物, 科学出版社, 北京, 1965, pp. 30～34.)

16 Liu, J. P.; Li, Y. Y.; Huang, X. T. Chem. Mater. 2008, 20, 250.

17 Pei, Z. W.; Su, Q.; Zhang, J. Y. J. Alloys Compd. 1993, 198, 51.

18 Zhou ,W. G.; Lu, M. K.; Gu, F. Mater. Lett. 2005, 59, 1020.

19 Liu, G. X.; Li, R. L.; Dong, X. T.; Wang, J. X.; Sun, D. Chin. J. Lumin. 2010, 31, 385 (in Chinese).(刘桂霞, 李若兰, 董相廷, 王进贤, 孙德, 发光学报, 2010, 31, 385.)

20 Liu, G. X.; Zhang, S.; Dong, X. T.; Wang, J. X. Acta Chim. Sinica 2010, 68, 1298 (in Chinese). (刘桂霞, 张颂, 董相廷, 王进贤, 化学学报, 2010, 68, 1298.)

21 Wei, Z. G.; Sun, L. D.; Liao, C. S.; Yin, J. L.; Jiang, X. C.; Yan, C. H. J. Phys. Chem. B 2002, 106, 10610.

22 Song, H. W.; Yu, H. Q.; Pan, G. H.; Bai, X.; Dong, B.; Zhang, X. T.; Hark, S. K. Chem. Mater. 2008, 20, 4762.

23 Li, Z. H.; Zeng, J. H.; Li, Y. D. Small 2007, 3, 438.
Options
Outlines

/

〈 〉