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Acta Chimica Sinica >

2012 , Vol. 0 >Issue 04: 519 - 524

DOI: https://doi.org/10.6023/A1109102

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Synthesis, Crystal Structure and Antibacterial Activity of A Bismuth(III) Complex [Bi2(PPA)6?(Phen)2] with Phenylacetic Acid and 1,10-Phenanthroline

  • Yang Shuping ,
  • Han Lijun ,
  • Pan Yan ,
  • Wu Zhenming ,
  • He Xinran ,
  • Chen Lijuan
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  • a School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005;
    b School of Mathematics and Science, Huaihai Institute of Technology, Lianyungang 222005;
    c Department of Pharmacology, School of Basic Medical Sciences and State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191

Received date: 2011-09-10

  Revised date: 2011-11-18

  Online published: 2011-12-19

Supported by

Project supported by the National Natural Science Foundation of China (No. 30901815) and Natural Science Foundation of Huaihai Institute of Technology, China (No. Z2009019).

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Abstract

A bismuth(III) complex [Bi2(PPA)6·(Phen)2] (HPPA ＝ phenylacetic acid; Phen ＝ 1,10-phenanthroline) was synthesized and characterized by elemental analysis and infrared (IR) spectroscopy, its crystal structure was determined by single crystal X-ray diffraction. The crystal of bismuth(III) complex belongs to triclinic system with space group P-1, a＝0.9100(6) nm, b＝1.2617(8) nm, c＝ 1.3324(9) nm, α＝89.757(8)°, β＝87.277(8)°, γ＝81.155(8)°, V＝1.5099(17) nm3, Dc＝1.748 g·cm-3, μ＝5.890 mm-1, Z＝1, F(000)＝780, residual factors R1＝0.0484, wR2＝0.1090 [I>2σ(I)], S＝1.002. The comcomplex is a binuclear bismuth(III) compound, and every bismuth(III) atom is nine-coordinated by six O atoms from three ligands (PPA) and two N atoms from one ligand (Phen) and one bridged O atom, and the coordination polyhedron around the bismuth(III) atom can be best described as a distorted tricapped trigonal-prismatic tetrakaidecahedron geometry, the valence sum of around Bi atom VBi(1)＝2.897. The distance of Bi…Bi is 0.4469(2) nm. The complex has a good effect against E. Coli, S. Aureus and B. Subtilis.

Key words： bismuth(III) complex; crystal structure; antibacterial activity; phenylacetic acid; 1,10-phenanthroline

Cite this article

Yang Shuping , Han Lijun , Pan Yan , Wu Zhenming , He Xinran , Chen Lijuan . Synthesis, Crystal Structure and Antibacterial Activity of A Bismuth(III) Complex [Bi2(PPA)6?(Phen)2] with Phenylacetic Acid and 1,10-Phenanthroline[J]. Acta Chimica Sinica, 2012 , 0(04) : 519 -524 . DOI: 10.6023/A1109102

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