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Acta Chimica Sinica >

2012 , Vol. 70 >Issue 07: 903 - 910

DOI: https://doi.org/10.6023/A1109032

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Synthesis of Cu2ZnSnS4 Nanocrystals and Its Third-order Nonlinear Optical Properties

  • Wang Yun ,
  • Liang Xiaojuan ,
  • Cai Qian ,
  • Feng Li ,
  • Shao Mingguo ,
  • Zhong Jiasong ,
  • Xiang Weidong
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  • a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035 China;
    b College of Materials Science and Engineering, Tongji University, Shanghai 201804 China

Received date: 2011-09-03

  Revised date: 2011-12-25

  Online published: 2012-04-23

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 50772075, 50972107) and Zhejiang Province Key Scientific and Technological Innovations Team of China (No. 2009R50010).

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Abstract

Monodisperse Cu2ZnSnS4 (CZTS) nanocrystals were synthesized by one-pot method using copper( II) acetylacetonate, zinc(II) acetate, tin(II) chloride, S powder and oleylamine as precursors. The composition, structure, morphology and properties of the CZTS were characterized by X-ray diffraction (XRD), energy dispersive X-ray (EDS), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), UV-vis and Z-scan technology. The results showed that the as-prepared CZTS nanocrystals were tetragonal phase with hexagonal shape and particle size about 10 nm. The nonlinear refraction index γ (-1.08×10-15, -9.08×10-17 m2·W-1), nonlinear absorption coefficient β (6.5×10-9, 3.69×10-11 m·W-1) and third-order optical susceptibility χ(3) (1.49× 10-9, 4.35×10-10 esu) of CZTS nanocrystals with different size (10 nm, 13 nm) were calculated. Finally, the growth mechanism of nanocrystals and the nonlinear optical properties were investigated.

Key words： Cu2ZnSnS4; nanocrystals; third-order nonlinear optical

Cite this article

Wang Yun , Liang Xiaojuan , Cai Qian , Feng Li , Shao Mingguo , Zhong Jiasong , Xiang Weidong . Synthesis of Cu2ZnSnS4 Nanocrystals and Its Third-order Nonlinear Optical Properties[J]. Acta Chimica Sinica, 2012 , 70(07) : 903 -910 . DOI: 10.6023/A1109032

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