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Ferrocene-anthracene Dyad Bearing Schiff base Donor and Its Multi-respond to Metal Ions

  • Zhao Xiaofang ,
  • Cao Qianyong ,
  • Lu Xin ,
  • Yang Zhenyu ,
  • Tang Jiancheng
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  • Department of Chemistry, Nanchang University, Nanchang 330031

Received date: 2011-10-11

  Revised date: 2011-12-07

  Online published: 2012-01-20

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21162017, 50801037).

Abstract

A new ferrocene-anthracene dyad bearing Schiff base donor, 1, has been synthesized and characterized. Its metal ions recognition ability was investigated by UV-Vis spectra, emission spectra and cyclic voltammetry (CV). Among various metal ions, 1 shows multi-respond to Cr3+, Cu2+ and Hg2+, with a ca. 100 nm red-shift of the low energy Fe(II)→Cp charge transfer located at 407 nm, which can be observed color change from yellow to red by naked eyes, and an anode shift of the Fe(II)/Fe(III) potential. In addition, 1 shows exclusive emission-on sensing to Cr3+.

Cite this article

Zhao Xiaofang , Cao Qianyong , Lu Xin , Yang Zhenyu , Tang Jiancheng . Ferrocene-anthracene Dyad Bearing Schiff base Donor and Its Multi-respond to Metal Ions[J]. Acta Chimica Sinica, 2012 , 70(07) : 838 -842 . DOI: 10.6023/A1110112

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