Special Topic

Preparation and Electrical-magnetic Properties of Zn0.6Mn0.2Ni0.2Fe2O4/poly(o-toluidine) Composites

  • Xiao Qiushi ,
  • Xu Qingqing ,
  • Li Liangchao ,
  • Qiu Haizhen ,
  • Chen Haifeng ,
  • Xu Feng
Expand
  • Department of Chemistry, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004

Received date: 2011-06-20

  Revised date: 2011-11-01

  Online published: 2011-12-14

Supported by

The project supported by the National Natural Science Foundation of China (No. 21071125) and the Science and Technology Key Project of Zhejiang Province (No. 2010C11053).

Abstract

Zn0.6Mn0.2Ni0.2Fe2O4 ferrite and their poly(o-toluidine) composites (ZMNF/POT) were prepared by a chemical precipitation method and an in situ polymerization method, respectively. Their composition, structure, morphology, conductivity and magnetic properties were characterized by means of modern testing technology. The results showed that the ZMNF particles were covered well by the POT, the conductivity of composites were mainly attributed to the POT content, while their magnetic properties were related to the ZMNF content. In the range of 1~15 MHz, the dielectric loss and conductivity of the POT and ZMNF/POT composites had better consistency with their conductivity; the magnetic loss of the composites was quite considerable and superior to that of the magnetic type ZMNF, and reached the maximum when the content of ZMNF is 31.74 wt% in the composites. The composites are hoped to used as advancing microwave absorption and shielding materials.

Cite this article

Xiao Qiushi , Xu Qingqing , Li Liangchao , Qiu Haizhen , Chen Haifeng , Xu Feng . Preparation and Electrical-magnetic Properties of Zn0.6Mn0.2Ni0.2Fe2O4/poly(o-toluidine) Composites[J]. Acta Chimica Sinica, 2012 , 70(06) : 728 -734 . DOI: 10.6023/A1106202

References

1 Burke, N. A. D.; Stover, H. D. H.; Dawson, F. P. Chem. Mater.2002, 14, 4752.  

2 Zhang, X.-Y.; Chen, Y.-J. J. Magn. Magn. Mater. 2004, 270,203.  

3 Kadam, S. L.; Kanamadi, C. M.; Patankar, K. K. Mater. Lett.2005, 59, 215.  

4 Fetisov, Y. K.; Bush, A. A.; Kamentsev, K. E. Solid State Commun. 2004, 132, 319.  

5 Peng, C.-H.; Wang, H.-W.; Kan, S.-W. J. Magn. Magn. Mater.2004, 284, 113.  

6 Shin, K. H.; Inoue, M.; Arie, K. I. Smart Mater. Struct.2000, 9, 357.  

7 Pieto, J. L.; Arora, C.; Lopez, E. J. Appl. Phys. 1996, 79,7099.

8 Michelena, M. D.; Montero, F.; Sanchez, P. J. Magn. Magn. Mater. 2002, 242, 1160.  

9 Ryu, J.; Priya, S.; Uchino, K. J. Electroceram. 2002, 8, 107.  

10 Nagamatsu, J.; Nakagawa, N.; Muranka, T.; Zenitani, Y.; Akimitsu, J. Nature 2001, 410, 63.  

11 Qiu, H.-Z.; Li, L.-C.; Xu, F.; Liu, H.; Wang, Y.-P. Chin. J. Nonferrous Met. 2008, 18, 1100 (in Chinese). (仇海珍, 李良超, 徐烽, 刘徽, 王育萍, 中国有色金属学报, 2008, 18, 1100.)  

12 Wang, L.-X.; Wang, F.-S. Acta Polym. Sinica 1989, (3), 264 (in Chinese). (王利祥, 王佛松, 高分子学报, 1989, (3), 264.)

13 Kilmartin, P. A.; Wright, G. A. Synth. Met. 1999, 104, 145.  

14 Tang, J.-S.; Jing, X.-B.; Wang, B.-C. Synth. Met. 1988, 24,231.  

15 Sun, D.-H.; Ding, J.-Q.; Zhang, Z.-P. China Plastics Industry1999, 127, 3 (in Chinese). (孙东豪, 丁进青, 张展屏, 塑料工业, 1999, 127, 3.)

16 Quillard, S.; Louarn, G.; Lefrant, S.; Macdiarmid, A. G. Phys. Rev. B: Condens. Matter 1994, 50, 12496.  

17 Waldron, R. D. Phys. Rev. 1955, 99, 1727.  

18 Hafner, S. R. Z. Kristallogr. 1961, 115, 331.  

19 Angeopoulos, M.; Ray, A.; MacDiarmid, A. G. ; Epstein, A, J. Synth. Met. 1987, 21, 21.  

20 Wan, M.-X.; Li, J.-C. J. Polym. Sci., Part A: Polym. Chem.1998, 36, 2799.  

21 Deng, J.-G.; He, C.-L.; Peng, Y.-X. Synth. Met. 2003, 139,295.

22 Deng, J.-G.; Ding, X.-B.; Zhang, W.-C. Polymer 2002, 43,2179.  

23 Yang, Q.-L.; Z, J.; Song, Y.-L. Chem. J. Chin. Univ. 2003,24, 2290 (in Chinese). (杨青林, 翟锦, 宋延林, 高等学校化学学报, 2003, 24,2290.)

24 Qian, R.-Y.; Ye, C. Polym. Bull. 1991, 2, 65 (in Chinese). (钱人元, 叶成, 高分子通报, 1991, 2, 65.)  
Outlines

/