Special Topic

Study on the Synthesis of Alkaline Ionic Liquids and Application for Baylis-Hillman Reaction

  • Yi Fengping ,
  • Zhang Xuan ,
  • Sun Haiyang ,
  • Chen Shihong
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  • a School of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418;
    b Department of Environmental Engineering, Jiangxi Environmental Engineering Vocational College, Ganzhou 341000

Received date: 2011-10-10

  Revised date: 2011-12-30

  Online published: 2012-01-20

Supported by

Project supported by the Key and Innovation Project of Shanghai Educational Committee (No. 11ZZ180) and the Project of Local University Ability Building of Shanghai Scientific and Technological Committee (No. 11520502600).

Abstract

The synthetic methods of alkaline ionic liquid hydroxide 1-butyl-4-dimethy1 aminopyridine were optimized by using orthogonal experimental. By using triethylene diamine (DABCO) as catalyst and alkaline ionic liquid as solvent, aromatic aldehydes with methyl acrylate’s Baylis-Hillman reaction was studied. Experimental results showed that fast reaction rate and high yield were obtained in the presence of the alkaline ionic liquid. On this basis, Baylis-Hillman reaction under the influence of water-ionic liquid composite system was further studied, and obtained better result.

Cite this article

Yi Fengping , Zhang Xuan , Sun Haiyang , Chen Shihong . Study on the Synthesis of Alkaline Ionic Liquids and Application for Baylis-Hillman Reaction[J]. Acta Chimica Sinica, 2012 , 70(06) : 741 -746 . DOI: 10.6023/A1110105

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