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Acta Chimica Sinica >

2012 , Vol. 70 >Issue 12: 1412 - 1416

DOI: https://doi.org/10.6023/A1112312

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Simple and Rapid Synthesis of Fe(PO3)3 with Three-dimensional Networks Morphology by a Novel Thermal Decomposition of Iron Phosphonate

  • Chen Lian ,
  • Zhang Yinghong ,
  • Zhou Yiming ,
  • Xie Kongwei ,
  • Chen Yu ,
  • Tang Yawen ,
  • Lu Tianhong
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  • a Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210046;
    b Department of Geological Engineering, Nanjing Engineering Vocational College, Nanjing 211135

Received date: 2011-12-31

  Revised date: 2012-04-25

  Online published: 2012-04-20

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21005039 and 21073094) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Abstract

The high pure Fe(PO3)3 with three-dimensional networks structure was synthesized by a novel thermal decomposition of phosphonate. Briefly, the iron phosphonate (FeIII-edtmpH5) complex was synthesized by using FeCl3 and ethylenediamine-tetramethylene phosphonic acid (edtmpH8) as starting materials. The composition and structure of FeIII-edtmpH5 complex is characterized by Fourier transform infrared spectroscopy (FT-IR), electrospray ionization/mass spectrometry (ESI/MS) and thermogravimetry-,differential thermal analysis (TG-DTA). Then, the Fe(PO3)3 is obtained by thermal decomposition of FeIII-edtmpH5 complex in air atmosphere. X-ray diffractometry (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) measurements show that the obtained Fe(PO3)3 possesses high purity, good crystallinity and particular three-dimensional networks morphology.

Key words： iron metaphosphate; phosphonate; complex; thermal decomposition

Cite this article

Chen Lian , Zhang Yinghong , Zhou Yiming , Xie Kongwei , Chen Yu , Tang Yawen , Lu Tianhong . Simple and Rapid Synthesis of Fe(PO3)3 with Three-dimensional Networks Morphology by a Novel Thermal Decomposition of Iron Phosphonate[J]. Acta Chimica Sinica, 2012 , 70(12) : 1412 -1416 . DOI: 10.6023/A1112312

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