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Acta Chimica Sinica >

2012 , Vol. 70 >Issue 10: 1187 - 1192

DOI: https://doi.org/10.6023/A1112153

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“Turn-on” Fluorescent Detection of 2,5-Di(4'-carboxylphenyl)-1-phenylpyrrole to Amines

  • Han Tianyu ,
  • Dong Yifan ,
  • Li Zeyu ,
  • Tong Bin ,
  • Shi Jianbing ,
  • Zhi Junge ,
  • Dong Yuping
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  • a College of Materials Science and Engineering, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081;
    b College of Chemistry, Beijing Institute of Technology, Beijing 100081

Received date: 2011-12-15

  Revised date: 2012-02-16

  Online published: 2012-02-28

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 51073026, 51061160500, 21074011) and the Research Fund for the Doctoral Program of Higher Education (No. 20091101110031).

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Abstract

2,5-Di(4'-carboxylphenyl)-1-phenylpyrrole was firstly successfully synthesized. UV-Vis and fluorescence spectra were employed to study the optical properties of TPP-2COONa at different pH values in aqueous media. The compound is found to weaken fluorescence in acidic state and, however, strengthen fluorescence in base state. The experimental results indicated that the fluorescent emission of TPP-2COOH can be “turned-on” by ammonia and some water-soluble alkyl amines (triethylamine, isopropylamine, diisopropylamine). But it remains unchanged upon addition of N-containing aromatic compounds (aniline, pyrrole, and pyridine). Specially, the compound as the fluorescent probe shows the good selectivity and sensitivity toward ammonia. Thus, the “on-line naked eye” detection for amines becomes possible.

Key words： triphenylpyrrole; turn-on detection; fluorescent probe; amine; water-soluble

Cite this article

Han Tianyu , Dong Yifan , Li Zeyu , Tong Bin , Shi Jianbing , Zhi Junge , Dong Yuping . “Turn-on” Fluorescent Detection of 2,5-Di(4'-carboxylphenyl)-1-phenylpyrrole to Amines[J]. Acta Chimica Sinica, 2012 , 70(10) : 1187 -1192 . DOI: 10.6023/A1112153

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