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Acta Chimica Sinica >

2013 , Vol. 71 >Issue 10: 1369 - 1372

DOI: https://doi.org/10.6023/A13050567

Communication

Pd3Bi2W22/SBA-15 as a Heterogeneous Catalyst for n-Hexadecane Oxidation

  • Cheng Yunfei ,
  • Chen Lifang ,
  • Qi Zhiwen ,
  • He Heyong
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  • a The Third Research Institute of Ministry of Public Security, Shanghai 200031;
    b State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237;
    c Department of Chemistry, Fudan University, Shanghai 200433

Received date: 2013-05-27

  Online published: 2013-08-14

Supported by

Project supported by the National Natural Science Foundation of China (No. 21006029), the Fundamental Research Funds for the Central Universities (No. 222201313007) and the Science and Technology Innovation Action of Shanghai (Nos. 11DZ0503600, 12DZ0503300).

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Abstract

[Pd3(H2O)9Bi2W22O76]8-/SBA-15 (Pd3Bi2W22/SBA-15) has been synthesized through[Pd3(H2O)9Bi2W22O76]8- anchored on 3-aminopropyltriethoxysilane (APTS)-modified mesoporous SBA-15. The catalyst was characterized by X-ray diffraction (XRD) and Fourier transform infrared reflectance (FT-IR) spectroscopy. The results showed that the catalyst exhibits high catalytic performance and reusability for the solvent-free aerobic oxidation of n-hexadecane to alcohols and ketones by using air as the oxidant under ambient conditions.

Key words： alkane oxidation; immobilization; SBA-15; Pd3Bi2W22; heterogeneous catalyst

Cite this article

Cheng Yunfei , Chen Lifang , Qi Zhiwen , He Heyong . Pd3Bi2W22/SBA-15 as a Heterogeneous Catalyst for n-Hexadecane Oxidation[J]. Acta Chimica Sinica, 2013 , 71(10) : 1369 -1372 . DOI: 10.6023/A13050567

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