Investigation of Gas Storage Properties of Graphene Material Prepared by Microwave-assisted Reduction of Graphene Oxide
Received date: 2014-02-12
Online published: 2014-02-25
Supported by
Project supported by Ministry of Science and Technology of China (Nos. 2012CB933401, 2011CB932602, 2011DFB50300) and Natural Science Foundation of China (Nos. 50933003, 50902073, 50903044).
Porous graphene material, named as MWRGO, has been prepared by microwave-assisted reduction method. Extensive characterizations indicate that graphene oxide was effectively reduced and MWRGO has a porous and disordered stacking structure. It has a special surface area of 461.6 m2/g with pore size centered at 0.67 nm. H2 and CO2 adsorption properties of MWRGO were investigated, showing a H2 uptake of 0.52 wt% at 77 K and 1 atm and an absolute adsorption amount as high as 10.7 wt% at a higher pressure of 60 bar. The amount of CO2 adsorption at 273 K and 1 atm is 7.1 wt%.
Key words： graphene; carbon materials; gas storage; microwave reduction; porous materials
Sui Dong , Huang Yi , Huang Lu , Zhang Yi , Chen Yongsheng . Investigation of Gas Storage Properties of Graphene Material Prepared by Microwave-assisted Reduction of Graphene Oxide[J]. Acta Chimica Sinica, 2014 , 72(3) : 382 -387 . DOI: 10.6023/A13080884
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