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Base Effects in Metal-Catalyzed Organic Reactions

  • Qin Guoping ,
  • Cui Chunming
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  • State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received date: 2014-12-01

  Online published: 2015-01-08

Supported by

Project supported by the National Natural Science Foundation of China (No. 21172116).

Abstract

Organic and inorganic bases have been widely employed in many metal-catalyzed organic reactions to promote the catalytic efficiency and improve the selectivity. In many cases, a certain base only works well for one type of reactions and roles of the base cannot be clearly understood at present. Professor Xi's group at Peking University recently summarized the roles of bases in many catalytic transformations and discussed the possible factors of bases on these transformations. This is the first review article on the systematic analysis of the base effects. This highlight, based on this review and the related references, will briefly discuss base effects on catalytic organic transformations.

Cite this article

Qin Guoping , Cui Chunming . Base Effects in Metal-Catalyzed Organic Reactions[J]. Acta Chimica Sinica, 2015 , 73(4) : 307 -309 . DOI: 10.6023/A14120828

References

[1] Ouyang, K. B.; Xi, Z. F. Acta Chim. Sinica 2013, 71, 13. (欧阳昆冰, 席振峰, 化学学报, 2013, 71, 13.)
[2] Yoo, W.-J.; Capdevila, M. G.; Du, X.; Kobayashi, S. Org. Lett. 2012, 14, 5326.
[3] (a) Zapf, A.; Beller, M. Chem. Eur. J. 2001, 7, 2908;
(b) Roger, J.; Po?gan, F.; Doucet, H. Adv. Synth. Catal. 2010, 352, 696;
(c) Derridj, F.; Roger, J.; Djebbar, S.; Doucet, H. Org. Lett. 2010, 12, 4320.
[4] Lafrance, M.; Rowley, C. N.; Woo, T. K.; Fagnou, K. J. Am. Chem. Soc. 2006, 128, 8754.
[5] Sunesson, Y.; Lime, E.; Lill, S. O.-N.; Meadows, R. E.; Norrby, P.-O. J. Org. Chem. 2014, 79, 11961.
[6] (a) Braga, A. A. C.; Morgon, N. H.; Ujaque, G.; Maseras, F. J. Am. Chem. Soc. 2005, 127, 9298;
(b) Yu, D.-G.; Shi, Z.-J. Angew. Chem., Int. Ed. 2011, 50, 7097;
(c) Chen, L.; Gao, Y. Q.; Russell, D. H. J. Phys. Chem. A 2012, 116, 689.
[7] (a) Allen, L. J.; Crabtree, R. H. Green Chem. 2010, 12, 1362;
(b) Liu, W.; Cao, H.; Zhang, H.; Zhang, H.; Chung, K. H.; He, C.; Wang, H.; Kwong, F. Y.; Lei, A. J. Am. Chem. Soc. 2010, 132, 16737;
(c) Zhang, H.; Shi, R.; Ding, A.; Lu, L.; Chen, B.; Lei, A. Angew. Chem., Int. Ed. 2012, 51, 12542;
(d) Zhang, J.; Bellomo, A.; Creamer, A. D.; Dreher, S. D.; Walsh, P. J. J. Am. Chem. Soc. 2012, 134, 13765.
[8] (a) Chen, I.-H.; Yin, Y.; Itano, W.; Kanai, K.; Shibasaki, M. J. Am. Chem. Soc. 2009, 131, 11664;
(b) Shirakawa, E.; Itoh, K.-I.; Higashino, T.; Hayashi, T. J. Am. Chem. Soc. 2010, 132, 15537.

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