Autoxidative Coupling and Its Applications to C-H Functionalization
Received date: 2014-12-25
Online published: 2015-03-04
Supported by
Project supported by the 973 Program(Nos. 2012CB725302, 2011CB808600), the National Natural Science Foundation of China(Nos. 21390400, 21272180, 21302148), and the Research Fund for the Doctoral Program of Higher Education of China(No. 20120141130002) and the Program for Changjiang Scholars and Innovative Research Team in University(No. IRT1030) and the Ministry of Science and Technology of China(No. 2012YQ120060). The Program of Introducing Talents of Discipline to Universities of China(111 Program) is also appreciated.
As a highly economic and efficient strategy for chemical bond formation, oxidative coupling has been widely applied in synthetic organic chemistry. Recently, Klussmann, Jiao and Huo et al. groups have successfully achieved the direct functionalization of Csp3-H and Csp2-H bonds through developing simple, elegant autoxidative coupling reactions, which makes a significant progress in this filed. This highlight mainly reviews the recent advances in autoxidative coupling.
Lu Qingquan , Yi Hong , Lei Aiwen . Autoxidative Coupling and Its Applications to C-H Functionalization[J]. Acta Chimica Sinica, 2015 , 73(12) : 1245 -1249 . DOI: 10.6023/A14120888
[1] (a) Ashenhurst, J. A. Chem. Soc. Rev. 2010, 39, 540.
(b) Liu, C.; Zhang, H.; Shi, W.; Lei, A. Chem. Rev. 2011, 111, 1780.
(c) Liu, Q.; Zhang, H.; Lei, A. Angew. Chem., Int. Ed. 2011, 50, 10788.
(d) Shi, W.; Liu, C.; Lei, A. Chem. Soc. Rev. 2011, 40, 2761.
(e) Zhang, D.; Qin, Y. Acta Chim. Sinica 2013, 71, 147.(张丹, 秦勇, 化学学报, 2013, 71, 147.)
(f) Sun, C.-L.; Li, B.-J.; Shi, Z.-J. Chem. Commun. 2010, 46, 677.
[2] (a) Guo, X.-W.; Li, Z.-P.; Li, C.-J. Prog. Chem. 2010, 22, 1434.(郭兴伟, 李志平, 李朝军, 化学进展, 2010, 22, 1434.)
(b) Li, C.-J. Acc. Chem. Res. 2009, 42, 335.
[3] Shi, Z.; Zhang, C.; Tang, C.; Jiao, N. Chem. Soc. Rev. 2012, 41, 3381.
[4] Pintér, Á.; Sud, A.; Sureshkumar, D.; Klussmann, M. Angew. Chem., Int. Ed. 2010, 49, 5004.
[5] (a) Li, B.-J.; Shi, Z.-J. Chem. Soc. Rev. 2012, 41, 5588.
(b) Sun, C.-L.; Li, B.-J.; Shi, Z.-J. Chem. Rev. 2010, 111, 1293.
[6] Pintér, Á.; Klussmann, M. Adv. Synth. Catal. 2012, 354, 701.
[7] Schweitzer-Chaput, B.; Sud, A.; Pintér, Á.; Dehn, S.; Schulze, P.; Klussmann, M. Angew. Chem., Int. Ed. 2013, 52, 13228.
[8] (a) Liu, L.; Wang, Z.; Fu, X.; Yan, C.-H. Org. Lett. 2012, 14, 5692.
(b) Piscopo, C. G.; Buhler, S.; Sartori, G.; Maggi, R. Catal. Sci. Technol. 2012, 2, 2449.
[9] Ueda, H.; Yoshida, K.; Tokuyama, H. Org. Lett. 2014, 16, 4194.
[10] Zhang, B.; Xiang, S.-K.; Zhang, L. H.; Cui, Y.; Jiao, N. Org. Lett. 2011, 13, 5212.
[11] Xu, Q.-L.; Gao, H.; Yousufuddin, M.; Ess, D. H.; Kürti, L. J. Am. Chem. Soc. 2013, 135, 14048.
[12] Huo, C.; Yuan, Y.; Wu, M.; Jia, X.; Wang, X.; Chen, F.; Tang, J. Angew. Chem., Int. Ed. 2014, 53, 13544.
[13] Kumar, S.; Rathore, V.; Verma, A.; Prasad, C. D.; Kumar, A.; Yadav, A.; Jana, S.; Sattar, M.; Meenakshi; Kumar, S. Org. Lett. 2015, 17, 82.
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