Dielectric Spectroscopy for the Study of the Dynamic Behavior of Polymer Chains
Received date: 2018-04-06
Online published: 2018-05-28
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21574053, 91333103).
Dielectric spectroscopy is a great useful method in investigating polymeric chains dynamic. It can reflect the characteristic structural information of molecules and is of great significance for revealing the nature and laws of the dynamic behavior of polymer chains as well as regulating their condensed structure. In this paper, based on the theory of dielectric spectroscopy, we conclude some kinds of common dielectric parameters and mathematic functions which is used to analyse the dielectric parameters. Therefore, the dielectric parameters of the polymeric chains, such as the dielectric constant, the dielectric relaxation strength, and the characteristic relaxation time of polymeric chains, can be obtained by analysing the relaxation process of the polymeric chains to estimate the scale of relaxation process, the relaxation groups and the cooperation process of side chains. Of course, it is very useful to connect the dielectric parameters with the Arrenius function, the Vogel-Tammann-Fulcher (VFT) and the statistics model to obtain the interface construction, the molecular internal composition, the dynamic behaviors of polymeric chain, and the dependence on environment etc., in order to establish a polymer physics theoretical foundation for the further macromolecule design, development and application for polymer materials.
Key words： dielectric spectroscopy; polymer; dynamic; feature parameters; relaxation
Lei Dong , Lu Dan . Dielectric Spectroscopy for the Study of the Dynamic Behavior of Polymer Chains[J]. Acta Chimica Sinica, 2018 , 76(8) : 605 -616 . DOI: 10.6023/A18040132
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