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Acta Chimica Sinica >

2020 , Vol. 78 >Issue 3: 217 - 231

DOI: https://doi.org/10.6023/A19110411

Review

Research Progress in the Stability of Inorganic Perovskite Solar Cells

  • Yang Ying ,
  • Lin Feiyu ,
  • Zhu Congtan ,
  • Chen Tian ,
  • Ma Shupeng ,
  • Luo Yuan ,
  • Zhu Liu ,
  • Guo Xueyi
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  • a School of Metallurgy and Environment, Central South University, Changsha 410083;
    b Hunan Key Laboratory of Nonferrous Metal Resources Recycling, Changsha 410083;
    c Hunan Engineering Research Center of Nonferrous Metal Resources Recycling, Changsha 410083;
    d First Rare Materials Co., Ltd, Guangdong 511500

Received date: 2019-11-22

  Online published: 2020-01-13

Supported by

Project supported by the National Natural Science Foundation of China (No. 61774169), Scientific Research Foundation for the Returned overseas Chinese Scholar; Postgraduate Independent Exploration and Innovation Projects of Central South University (Nos. 2019zzts944, 502211922).

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Abstract

In recent years, the efficiency of perovskite solar cells has developed rapidly, but its stability is limited by the influence of heat, light and water. All-inorganic perovskite formed by inorganic cations instead of organic cations shows improved thermal stability, high light absorption and adjustable band gap. The photoelectric conversion efficiency of all-inorganic perovskite solar cells has been improved to 19.03% at present. Among them, CsPbI3 perovskite solar cells have good photoelectric performance but poor stability, while CsPbBr3 perovskite solar cells have excellent stability but poor photoelectric performance of devices. In this paper, the influence of preparation method, film doping and interface modification on the stability of inorganic perovskite solar cells is systematically summarized. The reasons behind the instability of inorganic perovskite and the improvement methods are emphatically analyzed. In conclusion, improving the stability of inorganic perovskite light absorbing materials by film doping, surface passivation and morphology control such as low dimensional materials preparation can effectively improve the stability of the overall device, which provides the basis for further commercialization. In addition, it is of great significance to study the theory of charge transfer and recombination and establish a complete theoretical system for improving the performance and stability of the device. At present, most of perovskite contains harmful elements Pb. How to replace Pb and find new materials applied in perovskite solar cells is also the future development trend. In a word, as a new type of solar cell, inorganic perovskite solar cell is expected to contribute to the photovoltaic development of the future society.

Key words： inorganic perovskite solar cell; preparation method; interface modification; film doping; improved stability

Cite this article

Yang Ying , Lin Feiyu , Zhu Congtan , Chen Tian , Ma Shupeng , Luo Yuan , Zhu Liu , Guo Xueyi . Research Progress in the Stability of Inorganic Perovskite Solar Cells[J]. Acta Chimica Sinica, 2020 , 78(3) : 217 -231 . DOI: 10.6023/A19110411

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