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Acta Chimica Sinica >

2020 , Vol. 78 >Issue 9: 980 - 988

DOI: https://doi.org/10.6023/A20050165

Article

Synthesis of Two-dimensional Hydrophobic Copper-based Nanosheets and Their Application in Catalytic Oxidation of Sulfides

  • Yang Zhongjie ,
  • Zhang Xiaofei ,
  • Shi Yanan ,
  • Long Chang ,
  • Zhang Binhao ,
  • Yan Shuhao ,
  • Chang Lin ,
  • Tang Zhiyong
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  • a CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China;
    b School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
    c School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150080, China;
    d Sino-Danish Center for Education and Research, Sino-Danish College, University of Chinese Academy of Sciences, Beijing 100049, China

Received date: 2020-05-12

  Online published: 2020-07-10

Supported by

Project supported by the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB36000000), National Key Basic Research Program of China (No. 2016YFA0200700), National Natural Science Foundation of China (Nos. 21890381, 21721002), Frontier Science Key Project of Chinese Academy of Sciences (No. QYZDJ-SSW-SLH038), and K.C.Wong Education Foundation.

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Abstract

Two-dimensional nanomaterials have received extensive attention because of their unique physicochemical properties. However, bottom-up synthesis of two-dimensional (2D) stable nanomaterials still remains great challenge. In this work, a novel 2D metal-organic (Cu-BDT) nanosheet is constructed at room temperature by coordinative self-assembly, namely, using monovalent copper ion as the metal precursor and 1,4-benzenedithiol as organic ligand. As-synthesized Cu-BDT nanosheets are fully characterized by various techniques including powder-diffraction of X-rays (P-XRD), Fourier transform infrared spectrometer (FT-IR), Raman spectra (Raman), scanning electron microscopy (SEM), transmission electron microscope (TEM), atomic force microscope (AFM), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectrometer (ICP-OES) and contact angle test. The catalytic result verifies that the Cu-BDT nanosheet surfaces possess abundant active sites and good hydrophobicity, which facilitate oxidation of sulfides into sulfoxide compounds.

Key words： metal organic coordination complex; two-dimensional nanosheet; hydrophobicity; sulfides oxidation

Cite this article

Yang Zhongjie , Zhang Xiaofei , Shi Yanan , Long Chang , Zhang Binhao , Yan Shuhao , Chang Lin , Tang Zhiyong . Synthesis of Two-dimensional Hydrophobic Copper-based Nanosheets and Their Application in Catalytic Oxidation of Sulfides[J]. Acta Chimica Sinica, 2020 , 78(9) : 980 -988 . DOI: 10.6023/A20050165

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