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Acta Chimica Sinica >

2020 , Vol. 78 >Issue 9: 827 - 832

DOI: https://doi.org/10.6023/A20060227

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Exploration of Porous Organic Polymers as a Platform for Biomimetic Catalysis

  • Sun Qi ,
  • Xiao Feng-Shou
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  • a College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
    b Key Lab of Applied Chemistry of Zhejiang Province and Department of Chemistry, Zhejiang University, Hangzhou 310028, China

Received date: 2020-06-12

  Online published: 2020-07-17

Supported by

Project supported by the Fundamental Research Funds for the Central Universities (No. 17221012001) and the National Natural Science Foundation of China (No. 21720102001).

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Abstract

Nature has served as a dominant source of inspiration in the area of chemistry, serving as prototypes for the design of materials with proficient performance. In this account, we present our effort to explore porous organic polymers (POPs) as a platform for the construction of biomimetic catalysts to enable new technologies to achieve efficient conversions. For each aspect, we firstly describe the chemical basis of nature, followed by presenting the principles and design strategies involved for functionalizing POPs along with a summary of critical requirements for materials, culminating in a demonstration of unique features of POPs. Our endeavors of using POPs to address the fundamental scientific problems related to biomimetic catalysis are then presented to show their enormous potential and capabilities for a wide range of catalytic transformations. To conclude, a personal perspective on the challenges and opportunities in this emerging field are presented.

Key words： porous organic polymers; biomimetic design; secondary interaction; flexible framework; wettability control

Cite this article

Sun Qi , Xiao Feng-Shou . Exploration of Porous Organic Polymers as a Platform for Biomimetic Catalysis[J]. Acta Chimica Sinica, 2020 , 78(9) : 827 -832 . DOI: 10.6023/A20060227

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