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Acta Chimica Sinica >

2022 , Vol. 80 >Issue 4: 453 - 459

DOI: https://doi.org/10.6023/A21120598

Article

Investigation on the Luminescent Property and Application of In2BP3O12:Cr3+ Broadband Near-Infrared Phosphor※

  • Jingrong Zhang ,
  • Decai Huang ,
  • Congcong Huang ,
  • Sisi Liang ,
  • Haomiao Zhu
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  • a College of Chemistry and Materials, Fujian Normal University, Fuzhou 350003, China
    b CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on The Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
    c Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Xiamen 361021, China
    d Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341000, China
※ Dedicated to the 10th anniversary of the Youth Innovation Promotion Association, CAS.
* E-mail: ;
; Tel.: 0592-3594006

Received date: 2021-12-30

  Online published: 2022-02-07

Supported by

National Key R&D Program of China(2021YFB3500400); National Natural Science Foundation of China(11904363); Key Research Program of the Chinese Academy of Sciences(ZDRW-CN-2021-3)

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Abstract

Near-infrared (NIR) spectroscopy technique plays an important role in night-vision surveillance, food analysis, bioimaging and agriculture fields, and the development of compact and efficient NIR light source is a precondition for their massive commercial applications. Phosphor-converted light emitting diodes (pc-LED) have the advantages of compactness, low-cost, and long operating lifetime, thus have attracted considerable attentions in recent years. The key point is to exploit high performance NIR phosphors which can be excited efficiently by blue diode chips. A number of Cr3+-activated phosphors have been investigated aiming at NIR pc-LED applications. Nevertheless, most of the NIR phosphors show relatively short peak wavelength and narrow full width at half maximum (FWHM), resulting in spectral deficiency in the range 900~1100 nm. The phosphors with ultrabroad bandwidth are more desirable for spectroscopic applications. In this work, a novel broadband NIR light emitting phosphor In2BP3O12:Cr3+ is synthesized by solid state reaction method. The structure, concentration and temperature dependent luminescence properties, electron-phonon coupling as well as the NIR LED performances and applications of the In2BP3O12:Cr3+ have been investigated. Upon 480 nm excitation, the In2BP3O12:Cr3+ phosphor shows a broad emission band peaked at 950 nm and covering 750~1350 nm (bandwidth of ~210 nm), which is owing to the 4T2 → 4A2 transition of Cr3+ ions. It is found that the emission intensity of the phosphor at 373 K keep 40% of that at room temperature. A NIR pc-LED is packaged by combining the In2BP3O12:Cr3+ phosphor and a commercial blue InGaN chip, which generates broad NIR light emissions with an output power of ~5 mW at 60 mA drive current. When this NIR pc-LED is used to illuminate the human palm, the blood vessels in the palm are clearly imaged by a NIR charge coupled device (CCD) camera. These results suggest that the In2BP3O12:Cr3+ is a promising phosphor for fabricating NIR pc-LEDs, which are potential for non-destructive analysis in the fields of biology and medicine.

Key words： near infrared phosphor; In2BP3O12; LEDs; luminescent materials; broadband emission

Cite this article

Jingrong Zhang , Decai Huang , Congcong Huang , Sisi Liang , Haomiao Zhu . Investigation on the Luminescent Property and Application of In2BP3O12:Cr3+ Broadband Near-Infrared Phosphor※[J]. Acta Chimica Sinica, 2022 , 80(4) : 453 -459 . DOI: 10.6023/A21120598

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