Carbone Derivatives of Group 14: A Class of Important Reactive Intermediates
Received date: 2022-01-06
Online published: 2022-02-24
Supported by
National Natural Science Foundation of China(21925603); National Natural Science Foundation of China(21806167); National Natural Science Foundation of China(22176191)
The pursuit of unusual bonding environments of carbon species with non-octet electronic configurations has been quite active in fundamental organic and theoretical chemistry for many decades. In this respect, a distinct carbone species has been successfully isolated recently and defined as “carbodicarbene” or “bent allene.” Carbone is an important active intermediate since the synthesis of radical, carbene and carbyne. This neutral two-coordinated central carbon atom possesses two sets of lone pair electrons, possessing strong coordination ability. The present review introduces the discovery, fundamental properties and coordination chemistry of carbone. Meanwhile, the application of its relevant complexes in catalysis is introduced.
Kang Liu , Bin Li , Jipan Yu , Weiqun Shi . Carbone Derivatives of Group 14: A Class of Important Reactive Intermediates[J]. Acta Chimica Sinica, 2022 , 80(3) : 373 -385 . DOI: 10.6023/A21120592
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