Progress in Stimulus-Responsive Dendritic Gels※
Received date: 2022-08-19
Online published: 2022-09-14
Supported by
National Natural Science Foundation of China(21871270); National Natural Science Foundation of China(21472192); Doctor Research Fund of Shanxi Datong University(2019-B-01); Science Foundation of Shanxi Datong University(2020YGZX011); Open Research Fund of Key Laboratory of Marine Materials and Related Technologies, CAS(2021K02)
In recent years, stimulus-responsive supramolecular gels, as a class of smart soft matter materials, have shown very promising applications in the fields of ion recognition materials, self-healing materials, biomaterials and drug release, and have attracted increasing attentions. Dendrimers and dendrons are highly branched macromolecules with well-defined molecular architecture and have been widely used as building blocks in the self-assembling of supramolecular gel-phase materials. The unique dendritic architectures make the dendritic molecules as ideal candidates to be modified with various different functional moieties to develop multiple functional soft materials, which ensure each functionality to work independently without interfering. This characteristic makes them show unique advantages in the construction of stimuli- responsive gels, especially multiple stimuli-responsive gels. The research progress of stimuli-responsive dendritic gels is summarized in detail from the aspects of dendritic gel design, gel-formation mechanism, response performance and response mechanism. Based on the different stimulus, the stimulus-responsive dendritic gels are classfied into the following categories: light-responsive dendritic gel, redox-responsive dendritic gel, ion-responsive dendritic gel, thixotropic-responsive dendritic gel and multiple-responsive dendritic gel. In addition, the current challenges and perspectives on stimulus-responsive dendritic gels are also discussed.
Key words： supramolecular gels; dendrimer; stimuli-responsive; smart materials; progress
Zhixiong Liu , Qingkai Chu , Yu Feng . Progress in Stimulus-Responsive Dendritic Gels※[J]. Acta Chimica Sinica, 2022 , 80(10) : 1424 -1435 . DOI: 10.6023/A22080363
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