Research Progress in Precision Polymerization of Polar Olefin Monomers by Lewis Pairs★
Received date: 2023-05-04
Online published: 2023-06-07
Supported by
The National Natural Science Foundation of China(22225104); The National Natural Science Foundation of China(22071077); The National Natural Science Foundation of China(21871107); The National Natural Science Foundation of China(21975102)
As a newly emerged polymerization strategy, Lewis pair polymerization (LPP) has been widely used in the polymerization of polar olefin monomers and the preparation of functional materials in recent years. With its unique polymerization mechanism and kinetic characteristics, LPP has shown many advantages over the traditional polymerization methods, and accomplished many challenging tasks in polymer synthesis. This review systematically summarizes the research progress of the precision polymerization of the polar olefin monomers into polymers catalyzed by Lewis pairs in terms of molecular weight, molecular weight distribution, stereochemistry, monomer sequence and polymer topology, and proposes the outlook for the problems and challenges existing in the development of LPP.
Yi Wan , Jianghua He , Yuetao Zhang . Research Progress in Precision Polymerization of Polar Olefin Monomers by Lewis Pairs★[J]. Acta Chimica Sinica, 2023 , 81(9) : 1215 -1230 . DOI: 10.6023/A23050196
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