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Acta Chimica Sinica >

2023 , Vol. 81 >Issue 8: 955 - 966

DOI: https://doi.org/10.6023/A23040161

Perspective

Research Progress on Copper-Catalyzed Enantioselective Desymmetrization of Diols★

  • Zhanglong Yu ,
  • Zhongliang Li ,
  • Changjiang Yang ,
  • Qiangshuai Gu ,
  • Xinyuan Liu
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  • a Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055
    b Academy for Advanced Interdisciplinary Studies and Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055
    c Department of Chemistry, School of Sciences, Great Bay University, Dongguan 523000
★Dedicated to the 90th anniversary of Acta Chimica Sinica.
*E-mail: ;

Received date: 2023-04-23

  Online published: 2023-06-13

Supported by

National Natural Science Foundation of China(22025103); National Natural Science Foundation of China(92256301); National Natural Science Foundation of China(21831002); National Natural Science Foundation of China(22101122); National Natural Science Foundation of China(22001109); National Natural Science Foundation of China(22271133); National Natural Science Foundation of China(22201127); National Key R&D Program of China(2021YFF0701604); National Key R&D Program of China(2021YFF0701704); Shenzhen Science and Technology Program(KQTD20210811090112004); Shenzhen Science and Technology Program(JCYJ20220530115409020)

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Abstract

Enantioselective desymmetrization of diols is an important method for the synthesis of complex enantioenriched alcohols, which has broad application prospects in medicinal chemistry, total synthesis, and materials science. In recent years, the use of copper catalysis to achieve diols’ enantioselective desymmetrization has progressed rapidly because copper is inexpensive and readily available compared with other noble metal catalysts. Besides, copper undergoes a two-electron or single-electron transfer process in the catalytic cycle, and the rich oxidation states of copper provides the opportunity to solve some challenging problems. This review summarizes the research progress in this field according to the types of diols (meso diol and prochiral diol) and reactions together with a brief perspective.

Key words： copper catalysis; desymmetrization; diols; asymmetric catalysis

Cite this article

Zhanglong Yu , Zhongliang Li , Changjiang Yang , Qiangshuai Gu , Xinyuan Liu . Research Progress on Copper-Catalyzed Enantioselective Desymmetrization of Diols★[J]. Acta Chimica Sinica, 2023 , 81(8) : 955 -966 . DOI: 10.6023/A23040161

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