Modular Bifunctional Organoboron-ammonium/phosphonium Catalysts: Design and Catalytic Performance★
Received date: 2023-05-05
Online published: 2023-07-21
Supported by
National Natural Science Foundation of China(22101253); National Science Fund for Distinguished Young Scholars(T2225004)
Organoboron compounds are a class of non-metallic catalysts that have been extensively studied in recent years and have shown excellent applicability for ring-opening homopolymerization of epoxides and copolymerization of epoxides with other comonomers. However, the binary electrophile/nucleophile catalytic systems often have reduced activity or be deactivated due to the entropic disadvantage under dilute conditions, and it is also difficult to afford polymer materials with high molecular weight. This paper reviews the progress of bifunctional organoboron-quaternary ammonium/phosphonium salt catalytic systems containing both electrophilic and nucleophilic centers in one molecule that was designed by our group, focuses on the design concepts and principles of such bifunctional organoboron catalysts, compares the polymerization mechanisms between bifunctional and binary organoboron catalytic systems, and summarizes the use of bifunctional organoboron catalysts in the ring-opening polymerization of epoxides to prepare aliphatic polyethers, the copolymerization of epoxides and carbon dioxide/cyclic anhydride to prepare polycarbonates/polyesters. The future and trend of organoboron catalysts in polymer chemistry were prospected.
Key words： organoboron; Lewis pair; ring-opening polymerization; carbon dioxide; catalyst
Guan-Wen Yang , Guang-Peng Wu . Modular Bifunctional Organoboron-ammonium/phosphonium Catalysts: Design and Catalytic Performance★[J]. Acta Chimica Sinica, 2023 , 81(11) : 1551 -1565 . DOI: 10.6023/A23050206
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