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Acta Chimica Sinica >

2024 , Vol. 82 >Issue 6: 690 - 706

DOI: https://doi.org/10.6023/A24020061

Review

Research Progress on Room-temperature Solid-state Lithium Metal Batteries with Poly(ethylene oxide)-based Solid Polymer Electrolytes

  • Shijie Zhang ,
  • Duo Wang ,
  • Haoran Cui ,
  • Yalan Zhang ,
  • Hao Zhang ,
  • Zhixiang Yuan ,
  • Pengxian Han ,
  • Shuyu Yao ,
  • Lang Huang ,
  • Jianjun Zhang ,
  • Guanglei Cui
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  • a College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590
    b Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101
    c Qingdao No. 2 Middle School of Shandong Province, Qingdao 266061
    d Shandong Energy Institute, Qingdao 266101
    e Qingdao New Energy Shandong Laboratory, Qingdao 266101
* E-mail: ;
;
;
; Tel.: 0532-80662746; Fax: 0532-80662744

Received date: 2024-02-22

  Online published: 2024-04-02

Supported by

National Key R&D Program of China(2023YFC2812700); National Natural Science Foundation of China(52073298); National Natural Science Foundation of China(52273221); Youth Innovation Promotion Association of the Chinese Academy of Sciences(2020217); Qingdao New Energy Shandong Laboratory Open Project(QNESLOP202312)

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Abstract

Lithium-ion batteries are widely used in various fields of the national economy. However, those with liquid electrolytes may pose potential safety hazards, such as electrolytes leakage, volatilisation, combustion and even explosion. In contrast, solid-state lithium batteries with solid electrolyte exhibit high safety characteristics and have become a research and development hotspot in the scientific and industrial sectors. The design and development of solid-state electrolytes are crucial for solid-state lithium batteries. Poly(ethylene oxide) (PEO) solid polymer electrolyte (SPE) is an excellent electrolyte material for solid-state lithium-metal batteries (SSLBs) due to its high flexibility, excellent processability, good interfacial contact and compatibility with lithium-metal anode. However, the low room temperature ionic conductivity of PEO-based solid polymer electrolytes has seriously restricted its further development and application in the field of room temperature solid polymer lithium metal batteries. Through the continuous efforts of researchers at home and abroad, considerable progress has been made in the development of room-temperature solid-state lithium metal batteries SSLBs with PEO-based solid polymer electrolytes. A detailed description of the research progress room-temperature SSLBs with PEO-based solid-state polymer electrolytes is provided. The strategies covered include nanofiller composites, three-dimensional (3D) skeleton enhancement, molecular level modulation, blending with other polymers, and constructing fast ion transport channels inside the cathode. Finally, a systematic outlook on the challenges and future development trends room-temperature SSLBs with PEO-based solid polymer electrolyte are presented.

Key words： poly(ethylene oxide); solid polymer electrolyte; room temperature; efficient ion transport; solid-state lithium metal battery

Cite this article

Shijie Zhang , Duo Wang , Haoran Cui , Yalan Zhang , Hao Zhang , Zhixiang Yuan , Pengxian Han , Shuyu Yao , Lang Huang , Jianjun Zhang , Guanglei Cui . Research Progress on Room-temperature Solid-state Lithium Metal Batteries with Poly(ethylene oxide)-based Solid Polymer Electrolytes[J]. Acta Chimica Sinica, 2024 , 82(6) : 690 -706 . DOI: 10.6023/A24020061

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