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About the Cover:Silylenes are isoelectronic with carbenes and potentially powerful for molecular catalysis. The structural analysis discloses the strong interactions of the Si ligand with iron center, which is essential for the control and tuning of catalytic selectivity and activity. The combination of the abundant and nontoxic iron and silicon for catalysis is in line with the concept of the sustainable chemistry. [Cui, Chunming et al. on page 763-766.]
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