Ligand-Free Cu2O Nanowire Catalyzing C—N and C—O Coupling Reaction

doi:10.6023/cjoc201306020

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (1): 147-154.DOI: 10.6023/cjoc201306020 Previous Articles Next Articles

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无配体Cu₂O纳米线催化C—N/C—O偶联反应

董奇志, 向建南, 郭灿城

湖南大学化学化工学院化学生物传感与计量学国家重点实验室长沙 410082

收稿日期:2013-06-14 修回日期:2013-08-30 发布日期:2013-09-17
通讯作者: 向建南,郭灿城 E-mail: jnxiang@hnu.edu.cn; ccguo@hnu.edu.cn
基金资助:
湖南省自然科学基金（No. 13JJ5018）；湖南省科技厅支撑（No. 湘财企指（2009）76号）与长沙市科技局（No. 长财企指（No. 2012）64号）资助项目.

Ligand-Free Cu₂O Nanowire Catalyzing C—N and C—O Coupling Reaction

Dong Qizhi, Xiang Jiannan, Guo Cancheng

State Key Laboratory of Chem/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082

Received:2013-06-14 Revised:2013-08-30 Published:2013-09-17
Supported by:
Project supported by the Hunan Provincial Natural Science Foundation of China (No. 13JJ5018), the Key Technology R&D Program of Hnnan Provincial Science & Technology Department (No. 2009-76), the Changsha Science and Technology (No. 2012-64).

A novel nano-material with Cu₂O nanowires loaded on TiO₂ nanotubes (Cu₂O/TiO₂NTs) was prepared in this paper. The new type of catalyst was used to catalyze the C—N and C—O coupling of chlorinated aromatics. The results showed that this catalyst promised the reaction of not only aryl bromide, but also aryl chloride, and most products were synthesized in good to excellent yields. Moreover, the reused experiments confirmed that the catalyst can be recycled five times and present stable yields for reaction.

Key words: Cu₂O/TiO₂-catalyst, N-arylation;O-arylation, recycling

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Dong Qizhi, Xiang Jiannan, Guo Cancheng. Ligand-Free Cu₂O Nanowire Catalyzing C—N and C—O Coupling Reaction[J]. Chin. J. Org. Chem., 2014, 34(1): 147-154.

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无配体Cu₂O纳米线催化C—N/C—O偶联反应

Ligand-Free Cu₂O Nanowire Catalyzing C—N and C—O Coupling Reaction

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无配体Cu2O纳米线催化C—N/C—O偶联反应