Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (4): 735-740.DOI: 10.6023/cjoc201311023 Previous Articles     Next Articles

Articles

不饱和酮亚胺叶立德的分子内共轭加成

林敬, 程宇, 康泰然, 何龙, 刘全忠   

  1. 西华师范大学化学化工学院 化学合成与污染控制四川省重点实验室 南充 637009
  • 收稿日期:2013-11-13 修回日期:2013-12-16 发布日期:2014-01-02
  • 通讯作者: 刘全忠 E-mail:quanzhongliu@cwnu.edu.cn

Intramolecular Conjugate Additions of Unsaturated Ketimine Ylides for the Structurally Enriched 3,4-Dihydro-2H-pyrrole Derivatives

Lin Jing, Cheng Yu, Kang Tairan, He Long, Liu Quanzhong   

  1. Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637009
  • Received:2013-11-13 Revised:2013-12-16 Published:2014-01-02

The intramolecular conjugate additions of unsaturated ketimine ylides were firstly investigated. The corresponding structurally enriched 3,4-dihydro-2H-pyrrole derivatives were prepared in 67%~99% yields and 20:1 dr.

Key words: conjugate additions, ketimine ylides, 3,4-dihydro-2H-pyrrole derivatives