Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (6): 1061-1073.DOI: 10.6023/cjoc201312008 Previous Articles     Next Articles



曲红梅, 蒋丽丽, 陈涛, 唐建可   

  1. 天津大学化工学院 系统生物工程教育部重点实验室 天津市生物制药工程重点实验室 天津 300072
  • 收稿日期:2013-12-06 修回日期:2014-01-19 发布日期:2014-02-21
  • 通讯作者: 曲红梅
  • 基金资助:

    国家自然科学基金(No. 21102099)资助项目.

Research Progress in Benzosilole-Containing Organic Compounds

Qu Hongmei, Jiang Lili, Chen Tao, Tang Jianke   

  1. Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin Key Laboratory of Biological and Pharmaceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072
  • Received:2013-12-06 Revised:2014-01-19 Published:2014-02-21
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21102099).

Benzosilole-containing organic molecules have been potentially applied in opto-electronic material fields, due to their unique structural and optical characteristics. The rigid planar structures of acenes prevent conformational disorder, and extend the π-conjugation. Silacyclopentadiene can form σ** conjugation, lowering the LUMO and enhancing the electron affinity efficiently. In this review, benzosiloles, silicon-bridged stilbene derivatives, silafluorenes and bis-silicon-bridged p-terphenyls are focused on. The recent research progress in the synthesis, modification, properties and applications of benzosilole-containing organic compounds is summarized, and the future research of this field is also prospected.

Key words: benzosilole, silicon-bridge, π-conjugated, opto-electronic materials