Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 1885-1896.DOI: 10.6023/cjoc201804031 Previous Articles     Next Articles

Special Issue: 碳氢活化合辑2018-2019 元素有机化学合辑2018-2019



李园园a,b,d, 程玉华a, 单春晖c, 张敬e, 徐冬冬c, 白若鹏c, 屈凌波d, 蓝宇c,d   

  1. a 重庆第二师范学院生物与化学工程学院 重庆 400067;
    b 重庆第二师范学院脂质资源与儿童日化品协同创新中心 重庆 400067;
    c 重庆大学化学化工学院 重庆 401331;
    d 郑州大学化学与分子工程学院 郑州 450006;
    e 济宁学院化学与化工系 济宁 272001
  • 收稿日期:2018-04-16 修回日期:2018-05-11 发布日期:2018-05-17
  • 通讯作者: 蓝宇
  • 基金资助:


Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions

Li Yuanyuana,b,d, Cheng Yuhuaa, Shan Chunhuic, Zhang Jinge, Xu Dongdongc, Bai Ruopengc, Qu Lingbod, Lan Yuc,d   

  1. a College of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067;
    b Cooperative Innovation Center of Lipid Resources and Children's Daily Chemicals, Chongqing University of Education, Chongqing 400067;
    c School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331;
    d College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450006;
    e Department of Chemistry and Chemical Engineering, Jining University, Jining 272001
  • Received:2018-04-16 Revised:2018-05-11 Published:2018-05-17
  • Contact: 10.6023/cjoc201804031
  • Supported by:

    Project supported by the Basic and Frontier Research Project of Chongqing Science and Technology Commission (No. cstc2017jcyjAX0371), the Project of Science and Technology Collaborative Innovation Platform Construction of Chongqing University of Education (No. 2017XJPT01), the University-level Key Projects of Chongqing University of Education (No. KY201704A), and the Scientific Research Foundation of Chongqing University of Education (No. 2017BSRC001).

Alkaline-earth-metal compounds have been widely concerned due to its abundant reserve and the low-cost. In recent years, alkaline-earth-metal catalysis has achieved great progress in dehydrocoupling, hydroboration, hydrophosphination, hydroamination, hydrosilylation reactions experimentally and therotically. These types of reaction and catalytic mechanism, leading to indentify the role of alkaline-earth-metal in hydrogenation and dehydrogenation reaction are summarized. These reactions, in which the metal-hydride act as active species, generally undergo the reaction pathway involving the cleavage and formation of the metal-hydride covalent bond. The reaction features and mechanisms are generally recognized accrossing to the classification and discussion of these reactions, which would provide guidance for further development of alkaline-earth-metal catalysis.

Key words: alkaline-earth-metals catalyst, hydrofunctionalization reaction, mechanism study, recent advance