Study on Reaction of γ-Valerolactone and Amine Catalyzed by Zirconium-Based Lewis Acids

doi:10.6023/cjoc202003008

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (7): 2062-2070.DOI: 10.6023/cjoc202003008 Previous Articles Next Articles

锆基路易斯酸催化γ-戊内酯与胺的反应研究

孔庆山^a,b, 李兴龙^b, 许华建^a, 傅尧^b

a 合肥工业大学食品与生物工程学院合肥 230601;
b 中国科学技术大学化学系合肥微尺度物质科学国家实验室能源材料化学协同创新中心中国科学院城市污染物转化重点实验室安徽省生物质洁净能源重点实验室合肥 230026

收稿日期:2020-03-08 修回日期:2020-04-02 发布日期:2020-04-17
通讯作者: 许华建, 傅尧 E-mail:hjxu@hfut.edu.cn;fuyao@ustc.edu.cn
基金资助:
国家重点研发项目（No.2018YFB1501604）、国家自然科学基金（No.21472033）、安徽省重点科研开发项目（No.201904a07020069）、中央高校基础研究基金资助项目.

Study on Reaction of γ-Valerolactone and Amine Catalyzed by Zirconium-Based Lewis Acids

Kong Qingshan^a,b, Li Xinglong^b, Xu Huajian^a, Fu Yao^b

a School of Food and Biological Engineering, University of Science and Technology of China, Hefei 230601;
b Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, Chinese Academy of Sciences Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received:2020-03-08 Revised:2020-04-02 Published:2020-04-17
Supported by:
Project supported by the National Key Research and Development Program of China (No. 2018YFB1501604), the National Natural Science Foundation of China (No. 21472033), the Key Research and Development Program Projects in Anhui Province (No. 201904a07020069), and the Fundamental Research Funds for the Central Universities.

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Abstract

γ-Valerolactone (GVL) is an important biomass platform molecule, it can be converted into high value-added chemicals and fuel, which has important application prospects. This article describes a method for the synthesis of hydroxyamides and pyrrolidones from GVL and amine compounds by reductive amination/cyclization reactions under mild conditions using zirconium-based Lewis acid catalysts Zr-P-O and ZrOCl₂·8H₂O, respectively. In particular, a moderately high product yield can be obtained with the absence of a solvent. This method further lays the foundation for the application research of GVL.

Key words: γ-valerolactone, hydroxyamide, pyrrolidone, Lewis acid catalysis, zirconium-based catalyst

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Kong Qingshan, Li Xinglong, Xu Huajian, Fu Yao. Study on Reaction of γ-Valerolactone and Amine Catalyzed by Zirconium-Based Lewis Acids[J]. Chinese Journal of Organic Chemistry, 2020, 40(7): 2062-2070.

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锆基路易斯酸催化γ-戊内酯与胺的反应研究

Study on Reaction of γ-Valerolactone and Amine Catalyzed by Zirconium-Based Lewis Acids

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