Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (10): 3426-3430.DOI: 10.6023/cjoc202005022 Previous Articles     Next Articles

Special Issue: 黄乃正院士七十华诞专辑


欧阳瑶, 徐修华, 卿凤翎   

  1. 中国科学院上海有机化学研究所 分子合成卓越中心 有机氟化学重点实验室 上海 200032
  • 收稿日期:2020-05-09 修回日期:2020-06-03 发布日期:2020-06-10
  • 通讯作者: 卿凤翎
  • 基金资助:

Oxidative Coupling Reactions of Arylboronic Acids and Fluoroform-Derived AgCF3

Ouyang Yao, Xu Xiuhua, Qing Fengling   

  1. Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2020-05-09 Revised:2020-06-03 Published:2020-06-10
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21421002, 21991211) and the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB20000000).

A silver-mediated oxidative coupling reaction of arylboronic acids with fluoroform-derived AgCF3 using K2S2O8 as oxidant was developed. This reaction provides a new route to trifluoromethylated arenes.

Key words: oxidative trifluoromethylation, arylboronic acids, fluoroform, trifluoromethyl silver