Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (9): 3379-3389.DOI: 10.6023/cjoc202105036 Previous Articles     Next Articles



王鹏a,*(), 杨妲b, 刘欢b   

  1. a 中国科学院上海有机化学研究所 金属有机化学国家重点实验室 上海 200032
    b 中国石油大学(华东)理学院 化学系 山东青岛 266580
  • 收稿日期:2021-05-21 修回日期:2021-06-09 发布日期:2021-06-22
  • 通讯作者: 王鹏
  • 基金资助:
    国家自然科学基金青年(21901250); 中国博士后科学基金面上(2019M651625)

Recent Advances on Carbonylation of 1,3-Dienes

Peng Wanga(), Da Yangb, Huan Liub   

  1. a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
    b Department of Chemistry, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580
  • Received:2021-05-21 Revised:2021-06-09 Published:2021-06-22
  • Contact: Peng Wang
  • Supported by:
    National Natural Science Foundation of China: Youth Project(21901250); General Programs of China Postdoctoral Science Foundation(2019M651625)

1,3-Butadiene is the main component of C4 fraction in naphtha cracking process. The products of 1,3-butadiene carbonylation (hexanedial, adipic acid and dimethyl adipate) can be used in the production of nylon, plasticizer and pharmaceutical intermediates. How to efficiently and high chemo-/regio-selectivity synthesize these high value-added products has always been a difficult problem in organic chemistry research and industrial production. In this paper, the research progress of carbonylation (hydroformylation, hydroesterification, hydrocarboxylation) of 1,3-dienes (especially 1,3-butadiene) to construct high value-added chemicals in recent years is reviewed, then the difficulties and future development of this method are prospected.

Key words: 1,3-butadiene, hydroformylation, hydroesterification, syngas, homogeneous catalysis