Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (9): 2981-2987.DOI: 10.6023/cjoc202204034 Previous Articles     Next Articles



曾旭群, 张倩, 吴旭枫, 张静枫, 张鑫伟, 黄晓雷*()   

  1. 浙江师范大学化学与生命科学学院 先进催化材料教育部重点实验室 浙江金华 321004
  • 收稿日期:2022-04-14 修回日期:2022-05-20 发布日期:2022-06-08
  • 通讯作者: 黄晓雷
  • 基金资助:

Nickel-Catalyzed Heck Reaction of Cycloalkenes with Inert C—O Bonds of Aryl Carbonates and Aryl Sulfamates

Xuqun Zeng, Qian Zhang, Xufeng Wu, Jingfeng Zhang, Xinwei Zhang, Xiaolei Huang()   

  1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Department of Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004
  • Received:2022-04-14 Revised:2022-05-20 Published:2022-06-08
  • Contact: Xiaolei Huang
  • Supported by:
    Zhejiang Provincial Natural Science Foundation(LQ22B020002)

An efficient nickel-catalyzed Heck reaction of cycloalkenes with inert C—O bonds of aryl carbonates and sulfamates has been developed. Naphthyl, heterocycles and simple phenyl substituted carbonates with various functional groups are compatible with the catalytic systems comprising Ni(II), PhBPE ligand and reductive metal Zn.

Key words: nickel, Heck reaction, aryl carbonates, aryl sulfamates