Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases

doi:10.6023/cjoc202401004

Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (6): 1831-1852.DOI: 10.6023/cjoc202401004 Previous Articles Next Articles

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关于惰性含氟温室气体转化与利用的研究进展

邹震雷^a^,^b,†, 李和寅^b,†, 黄梦君^b, 沈胤朴^b, 刘继阳^b, 王之兆^b, 张为钢^b^,^*(), 王毅^b^,^*(), 潘毅^b

a 铜陵学院电气工程学院光电子应用安徽省工程技术研究中心仿生能源实验室安徽铜陵 244000
b 南京大学化学化工学院配位化学国家重点实验室江苏省先进有机材料重点实验室南京 210033

收稿日期:2024-01-05 修回日期:2024-02-02 发布日期:2024-02-27
作者简介:
^†共同第一作者
基金资助:
国家自然科学基金(21971107); 国家自然科学基金(22071101); 国家自然科学基金(22271147); 铜陵学院基金(2023tlxyrc15)

Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases

Zhenlei Zou^a^,^b,†, Heyin Li^b,†, Mengjun Huang^b, Yinpu Shen^b, Jiyang Liu^b, Zhizhao Wang^b, Weigang Zhang^b,*(), Yi Wang^b,*(), Yi Pan^b,*

a AnHui Technology Research Center of Optoelectronic Technology Appliance, Biomimetic Energy Laboratory, School of Electrical Engineering, Tongling University, Tongling, Anhui 244000
b State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210033

Received:2024-01-05 Revised:2024-02-02 Published:2024-02-27
Contact: * E-mail: zwgqlsfxy@163.com;yiwang@nju.edu.cn
About author:
^†These authors contributed equally to this work.
Supported by:
National Natural Science Foundation of China(21971107); National Natural Science Foundation of China(22071101); National Natural Science Foundation of China(22271147); Foundation of Tongling University(2023tlxyrc15)

Over the past few decades, fluorinated greenhouse gases have been used almost everywhere in human society due to their special physical and chemical properties. In spite of the convenience they provide to peopleʼs production and life, they also cause many environmental problems. The relevant studies have shown that the release of fluorinated gases causes a more serious greenhouse effect than normal greenhouse gases. Therefore, the use of fluorinated gases must be reassessed. In order to maximize the economic benefits of fluorinated gases and reduce their environmental pollution, scientists all over the world are trying to develop new methods for the conversion and utilization of fluorinated greenhouse gases. we aim to provide an overview of the conversion and utilization of fluorinated greenhouse gases, such as freon, sulfuryl fluoride, nitrogen trifluoride and sulfur hexafluoride from 2000 to 2023.

Key words: inert fluorinated greenhouse gas, freon, sulfuryl fluoride, nitrogen trifluoride, sulfur hexafluoride

Cite this article

Zhenlei Zou, Heyin Li, Mengjun Huang, Yinpu Shen, Jiyang Liu, Zhizhao Wang, Weigang Zhang, Yi Wang, Yi Pan. Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases[J]. Chinese Journal of Organic Chemistry, 2024, 44(6): 1831-1852.

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Fig. & Tab. 39

Scheme 1. Conversion and use of inert fluorinated greenhouse gases

Scheme 2. Carbine activation model for Freon-22

Scheme 3. Continuous flow synthesis of ketodifluoroolefins and deuterodifluoromethyl alcohols based on Freon-22

Scheme 4. Strategies for photocatalytic trimethylaminoborane activation of Freon-22

Scheme 5. Possible mechanisms of the photocatalytic trimethylaminoborane activation strategy for Freon-22

Scheme 6. Strategy for the activation of Freon-22 by the phase transfer catalyst tetraphenylarsenic chloride

Scheme 7. Palladium-catalyzed coupling reactions involving phenylboronic acid and ClCF2H

Scheme 8. Palladium-catalyzed coupling reactions involving aryl bromides and ClCF2H

Scheme 9. Palladium-catalyzed coupling reactions involving phenylacetylene and ClCF2H

Scheme 10. Nickel-catalyzed reduction coupling reactions involving aryl chlorides and ClCF2H

Scheme 11. Copper-catalysed asymmetric difluoromethylation of amino acid derivatives

Scheme 12. Traditional activation modes of fluoroform and important nucleophilic trifluoromethyl reagents

Scheme 13. Copper-catalyzed asymmetric difluoromethylation of amino acid derivatives

Scheme 14. Synthesis of fluorosulfonates and fluorosulfonamides

Scheme 15. Derivatisation of fluorosulfonates

Scheme 16. Nucleophilic substitution and metal coupling reactions involving aryl fluorosulfonates

Scheme 17. Construction of the C—SO2F bond

Scheme 18. Novel sulfonylfluorimidazole salt reagents for the construction of N—SO2F, O—SO2F bonds

Scheme 19. Photocatalytic synthesis of alkenylsulfonyl fluoride based on fluorochlorosulfonyls

Scheme 20. Photochemical and electrochemical reaction applications of fluorochlorosulfonyls

Scheme 21. Photocatalytic reaction synthesis strategy based on IMSF reagents

Scheme 22. Strategies for the synthesis of sulfonyl fluoroborides based on IMSF reagents

Scheme 23. Photochemical synthesis strategies based on FABI reagents

Scheme 24. Previous activation modes of NF3

Scheme 25. Strategy for the synthesis of perfluorinated amines based on NF3

Scheme 26. Diverse transformations of NF3

Scheme 27. Deoxyfluorination of allyl alcohols

Scheme 28. SF6 activation strategy based on Pt complexes

Scheme 29. SF6 activation strategy based on bipyridines

Scheme 30. SF6 activation strategy based on nitrogen carbene

Scheme 31. SF6 activation strategy based on nitrogen carbene

Scheme 32. Photoredox Catalytic Activation of SF6 based on phenothiazine

Scheme 33. Photoredox catalytic activation of SF6 based on benzophenone

Scheme 34. Electrochemical strategy to activate SF6

Scheme 35. Multifunctional conversion based on TDAE-SF5-F reagent

Scheme 36. Unsaturated bond addition reactions involving SF5Cl

Scheme 37. Selective construction of α-SF5 carbonyl compounds by SF5Cl and diazo compounds

Scheme 38. Three-component reaction involving SF5Cl, diazo compounds and alkenes

Scheme 39. Multifunctional conversion based on TDAE-SF5-F reagent

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关于惰性含氟温室气体转化与利用的研究进展

Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases

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