Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (6): 539-542. Previous Articles     Next Articles

在氢化钙-硅胶存在下的烯丙醇催化不对称环氧化

周维善;吴日南;王志民   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1988-12-25

The catalytic epoxidation of allylic alcohols in the presence of calcium hydride and silica gel

ZHOU WEISHAN;WU RINAN;WANG ZHIMIN   

  • Published:1988-12-25

In the asym. epoxidn. of allylic alcs. with catalytic amount of Ti(OCHMe)4-diisopropyl tartrate and in the presence of catalytic amts. of calcium hydride (10%) and silica gel (15%), the reaction time was not significantly reduced. The epoxidn. of six primary allylic alcs. and the kinetic resoln. of dl-3-octen-2-ol are described.

CLC Number: