Study on the syntheses, structures and chemistry of η^6-arene organolanthanoids II: Synthesis and structure of Sm(η^6-CH3C6H5)(η ^2-AlCl4)3

Chin. J. Org. Chem. ›› 1989, Vol. 9 ›› Issue (5): 414-417. Previous Articles Next Articles

η^6-芳烃稀土有机配合物的合成, 结构及性能研究 II: Sm(η^6-CH3C6H5)(η^2-AlCl4)3的合成及晶体结构

范宝臣;沈琪;林永华

中国科学院长春应用化学研究所

发布日期:1989-10-25

Study on the syntheses, structures and chemistry of η^6-arene organolanthanoids II: Synthesis and structure of Sm(η^6-CH3C6H5)(η ^2-AlCl4)3

FAN BAOCHEN;SHEN QI;LIN YONGHUA

Published:1989-10-25

Abstract

Sm(h6-CH3C8H5)(h2-AlCl4)3 was prepared by reacting activated AlCl3 and aluminum powder with SmCl3 in toluene. The x-ray structure was determine The center metal atom Sm(III) bonds to six carbon atoms in the toluene ring and six chlorine atoms. The average Sm-C distance and Sm-Cl distance are 2.91 ?and 2.84 ? resp. The deviation between the six Sm-C distances is much larger than that in Sm(h6-C6H6)(h2-AlCl4)3, this is due to the steric interaction between the Me group in the toluene ring and the equatorial chlorine atoms.

Key words: CRYSTAL STRUCTURE DETERMINATION, ALUMINIUM CHLORIDE, LANTHANON, BENZENE P, STRUCTURE AND PROPERTY CORRELATION, RARE EARTH METAL COMPLEX, SAMARIUM COMPLEX

CLC Number:

O611.662

Cite this article

FAN BAOCHEN;SHEN QI;LIN YONGHUA. Study on the syntheses, structures and chemistry of η^6-arene organolanthanoids II: Synthesis and structure of Sm(η^6-CH3C6H5)(η ^2-AlCl4)3[J]. Chin. J. Org. Chem., 1989, 9(5): 414-417.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Jinsong Hou, Gaosheng Yang. Reaction of Tandem Addition of Aliphatic Amines to Alkenylnitriles Catalyzed by Tris(o-dimethylaminobenzyl)yttrium [J]. Chinese Journal of Organic Chemistry, 2022, 42(7): 2070-2078.
[2]	Bing Bai, Fanglin Xu, Jing Yang, Gaihong Zhang, Duobin Mao, Ning Wang. Synthesis of 3-(2-Aminoethyl)pyrroles Catalyzed by AlCl₃ [J]. Chinese Journal of Organic Chemistry, 2021, 41(6): 2335-2342.
[3]	Zhai Jiaojiao, Yao Zhigang, Xu Fan. Efficient Synthesis of 3-Azaarene-substituted 3-Hydroxy-2-oxindoles via Aluminium Chloride Catalyzed sp³-C—H Functionalization [J]. Chin. J. Org. Chem., 2014, 34(8): 1639-1645.
[4]	Liu Taiqi;Ding Fuchen;Lin Yonghua;Yu Jianxiang;Shi Qisong;Shen Qi. A Novel Reaction of (CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb) with Cyclopentadiene Forming (C_5H_5)_3Ln·THF [J]. Chin. J. Org. Chem., 2003, 23(9): 1029-1032.
[5]	Yuan Fugen;Chen Li;Wen Linhong;Yang Jing. Synthesis and Molecular Structure of Bis(cyclopentadienyl) Cyclohexyloxy Lanthanide Compounds and Their Catalytic Activity [J]. Chin. J. Org. Chem., 2003, 23(7): 646-649.
[6]	Zhou Wenfu;Sun Heqi. Study on the QSAR of Biiodegradationh Toxicol of Nitrobenzene Derivatives with Their FMO Potential Charge Density Energies S_(Ei)~ (HO) [J]. Chin. J. Org. Chem., 2003, 23(7): 705-709.
[7]	Ji ShunJun;Lang JiangPing;Wang ShunYi;Huang XiaoYing. Recent Developments of Photochemical Reaction for Halogenated Compounds [J]. Chin. J. Org. Chem., 2003, 23(4): 393-401.
[8]	Zhang TianLin;Wu YaMing. Synthesis of 1,4-Bis｛2-［4-(2-benzoxazolyl) phenyl］viny ｝benzene and Its Derivatives [J]. Chin. J. Org. Chem., 2003, 23(4): 350-352.
[9]	Qiu Xiyuan. Studies on the Reaction Conditions and Mechanism of Electroorganic Synthesis of 1,4-Bis [ 2- (3,4,5-trimethoxyphenyl) vinyl ] benzene [J]. Chin. J. Org. Chem., 2003, 23(3): 258-264.
[10]	He Shuiyang;Chen Junli;Yang Rui;Wu Wangting;Zhao Jianshe;Wang Ruxian;Wang Ruxian. Synthesis, Spectrum Study and Biological Activity of Salicylaldehyde Salicylhydrazone Complexes with Rare Earth [J]. Chin. J. Org. Chem., 2003, 23(12): 1387-1392.
[11]	Chen Xiangqun;Huang Yudong;Li Dawei. Synthesis and Purification of 2,6-Bis(p-aminophenyl)-benzo[1,2-d;5, 4-d']bisoxazole [J]. Chin. J. Org. Chem., 2003, 23(11): 1306-1308.
[12]	Zhao Ying;Yang Zhi;Tang Lin. Organic Reactions Catalyzed by Aluminum Chloride [J]. Chin. J. Org. Chem., 2003, 23(11): 1219-1229.
[13]	Chen Ruifang;Kazuyuki Tatsumi. Synthesis and molecular structure of a novel dilithium complex with (i-Pr_2C_6H_3)_2-dad ligand [J]. Chin. J. Org. Chem., 2002, 22(4): 272-274.
[14]	Yin Handong;Zhang Rufen;Wang Yong;Ma Chunlin. Synthesis and properties of bis (triphenylgermanium) dicarboxylates [J]. Chin. J. Org. Chem., 2001, 21(7): 530-532.
[15]	Wang Zhenjun;Dong Faxin;Lu Jun;Liu Jianrui;Ma Huairang. Study on the synthesis of [2,2]-paracyclophane [J]. Chin. J. Org. Chem., 2001, 21(7): 538-540.

η^6-芳烃稀土有机配合物的合成, 结构及性能研究 II: Sm(η^6-CH3C6H5)(η^2-AlCl4)3的合成及晶体结构

Study on the syntheses, structures and chemistry of η^6-arene organolanthanoids II: Synthesis and structure of Sm(η^6-CH3C6H5)(η ^2-AlCl4)3

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments