An one-pot synthesis of 1-hydroxy-3-phenyl allyl phosphonates (phosphinates)

Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (3): 247-251. Previous Articles Next Articles

Original Articles

一锅反应合成1-羟基-3-苯基烯丙基膦(次膦)酸酯

李玉桂;刘云山;刘斌;石国柱

南开大学元素有机化学研究所

发布日期:1990-06-25

An one-pot synthesis of 1-hydroxy-3-phenyl allyl phosphonates (phosphinates)

LI YUGUI;LIU YUNSHAN;LIU BIN;SHI GUOZHU

Published:1990-06-25

Abstract

The title compounds were synthesized in high yield by an one-pot reaction of phosphites (phosphinates) with cinnamaldehyde, excess Me3SiCl, and Et3N in DME. The procedure was carried out under very mild condition and there was almost no side reaction.

Key words: ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, PHOSPHONIC ACID ESTER, TRIETHYL AMINE, BENZENE P, NMR SPECTROMETRY, ONE-STEP METHOD, CHLOROSILANE, ALLYL GROUP

CLC Number:

O621

Cite this article

LI YUGUI;LIU YUNSHAN;LIU BIN;SHI GUOZHU. An one-pot synthesis of 1-hydroxy-3-phenyl allyl phosphonates (phosphinates)[J]. Chin. J. Org. Chem., 1990, 10(3): 247-251.

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一锅反应合成1-羟基-3-苯基烯丙基膦(次膦)酸酯

An one-pot synthesis of 1-hydroxy-3-phenyl allyl phosphonates (phosphinates)

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