share
Chin. J. Org. Chem. ›› 1994, Vol. 14 ›› Issue (3): 265-269. Previous Articles Next Articles
Original Articles
钱长涛;王兵;邓道利
发布日期:
QIAN CHANGTAO;WANG BING;DENG DAOLI
Published:
Share
The complexes (CH~3OCH~2CH~2C~5H~4)~2Ln(C~5H~5) (Ln=La,Pr,Nd) were synthesized via the reaction of bis (2-methoxylethylcyclopentadienyl) chlorides of early lanthanide with sodium cyclopentadienyl in THF. The new complexes were identified by IR, ^1H NMR, ^1^3C NMR, MS, XPS and elemental analyses. Reduction of 1-hexene with different tricyclopentadienyl lanthanides / NaH system was investigated. The reducing activity depends strongly upon the coordination sphere of the rare earth ion.
Key words: REACTION PROPERTIES
CLC Number:
O627
QIAN CHANGTAO;WANG BING;DENG DAOLI. Synthesis and reactivity of (CH~3OCH~2CH~2C~5H~4)~2 Ln(C~5H~5)[J]. Chin. J. Org. Chem., 1994, 14(3): 265-269.
Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks