share
Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (1): 60-63. Previous Articles Next Articles
Original Articles
尹鹤群;吴国生;马云飞
发布日期:
YIN HEQUN;WU GUOSHENG;MA YUNFEI
Published:
Share
A synthetic route of the title compound, a new dihydrogenated derivative of lavendulol, starting with readily available isoanyl from the distillation residue in the ethanol production process with sugarhouse molasses in South China is described. Phase-tramsfer catalytic condensation of isoamyl chloride with acetone gave 6-methyl-2-heptanone in a yield of 43% , which upon methylation and dehydrochlorination led to 2,6-dimethyl-2-heptene. Prins reaction of the alkene with paraformaldehyde in stannic chloride-dichloromethane afforded the final product in a yield of 41.2% . Dihydro (4,5) lavandulol seems to be a mimic with nice but a little milder lavender scent.
Key words: ISOAMYL ALCOHOL, LAVANDULOL, ENVIRONMENTAL PROTECTION
CLC Number:
O621
YIN HEQUN;WU GUOSHENG;MA YUNFEI. synthesis of dihydro-4,5-lavandulol[J]. Chin. J. Org. Chem., 1995, 15(1): 60-63.
Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks