Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (3): 263-267. Previous Articles     Next Articles

Original Articles

C~s-三高立方烷-8,11-二酮-1,9-二羧酸酯衍生物的合成

管晓培;于永忠   

  1. 北京理工大学化工与材料学院
  • 发布日期:1995-06-25

Synthesis of C~s-trishomocubane-8,11-dione-1,9- dicarboxylate derivatives

YU YONGZHONG   

  • Published:1995-06-25

The Diels-Alder cycloaddition of benzoquinone-2,5- dicarboxylates with cyclopentadiene derivatives was studied in detail. Photocycloaddition of the corresponding Diels-Alder adducts afforded C~s-trishomocubane derivatives; in the case of adduct 6, the Paterno-Buchi adduct 7 became dominant.

Key words: CARBOXYLIC ACID ESTER, CUBANE, DIELS-ALDER REACTION

CLC Number: