Preparation of polystyryl diphenyl phosphine copper(Ⅰ) tetrahydroborate and reduction of acyl chloride

Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (6): 622-626. Previous Articles Next Articles

Original Articles

聚苯乙烯-二苯基膦-铜(Ⅰ)-四氢化硼络合物的制备及其对酰氯的还原

熊桂荣;黄锦霞;张万轩;陈家威

武汉市乡镇企业管理局科技处;湖北大学化学系

发布日期:1995-12-25

Preparation of polystyryl diphenyl phosphine copper(Ⅰ) tetrahydroborate and reduction of acyl chloride

XIONG GUIRONG;HUANG JINXIA;ZHANG WANXUAN;CHEN JIAWEI

Published:1995-12-25

Abstract

A few polystyryl diphenyl copper(Ⅰ) Tetrahydroborate complexes (PDPCT) were prepared using various crosslinking (1%, 2%, 4%, 7%, 8%, 12%) polystyrene beads as supports. Their contents and structures were tested and analyzed, which their behavior reducing benzoyl chlo-ride, cinnamoyl chloride, p-nitrobenzoyl chloride to the corresponding aldehydes or alcohols in the different conditions of temperature, solvent and catalyst and recovering were studied.

Key words: INFRARED SPECTROPHOTOMETRY, HIGH SPEED LIQUID CHROMATOGRAPHY, DIPHENYLPHOSPHINE, POLYSTYRENE, COPPER COMPLEX, REDUCER, ACYL CHLORIDES

CLC Number:

O611.662

Cite this article

XIONG GUIRONG;HUANG JINXIA;ZHANG WANXUAN;CHEN JIAWEI. Preparation of polystyryl diphenyl phosphine copper(Ⅰ) tetrahydroborate and reduction of acyl chloride[J]. Chin. J. Org. Chem., 1995, 15(6): 622-626.

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聚苯乙烯-二苯基膦-铜(Ⅰ)-四氢化硼络合物的制备及其对酰氯的还原

Preparation of polystyryl diphenyl phosphine copper(Ⅰ) tetrahydroborate and reduction of acyl chloride

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