Pentamethylcyclopentadienyl halfsandwich rhodium complexes containing 1,1'- ferrocene dichalcogenido chelate ligands

Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (2): 202-205. Previous Articles Next Articles

含半夹心结构铑的1,1'-二硫(硒、碲)二茂铁化合物

金国新;刘宇;于晓燕

中国科学院长春应用化学研究所.长春(130022)

发布日期:2000-04-25

Pentamethylcyclopentadienyl halfsandwich rhodium complexes containing 1,1'- ferrocene dichalcogenido chelate ligands

Jin Guoxin;Liu Yu;Yu Xiaoyan

Changchun Inst Appl Chem., CAS.Changchun(130022)

Published:2000-04-25

Abstract

The heterobimetallic complexes Cp*Rh(CN^tBu) (EC5H4)2Fe[E=S(2), Se(3), Te(4)] have been synthesized by the reaction of halfsandwich rhodium complex Cp*Rh(CN^tBu) Cl2 with Fe(C5H4ELi)2. 2THF. Oxidation of 2,3 by AgBF4 to give ferrocenium - type salts [Cp*Rh(CNtBu) (EC5H4)2Fe] + [BF4]^-[E=S(5), Se(6)] also occurs readily. The new complexes have been characteried by MS IR、^1H and ^1^3C NMR spectroscopy and elemental analysis.

Key words: SANDWICH COMPOUNDS, FERROCENE P, SELENIUM COMPOUNDS, TELLURIUM COMPOUNDS, SULFUR COMPOUNDS, ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, PROTON MAGNETIC RESONANCE SPECTROMETRY, MASS SPECTROGRAPHY

CLC Number:

O627

Cite this article

Jin Guoxin;Liu Yu;Yu Xiaoyan. Pentamethylcyclopentadienyl halfsandwich rhodium complexes containing 1,1'- ferrocene dichalcogenido chelate ligands[J]. Chin. J. Org. Chem., 2000, 20(2): 202-205.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Shan Li, Yuan Cao, Lüqi Jiang. Recent Progress on Alkyl-, Aryl- and Fluoroalkyl-selenylation Reactions [J]. Chinese Journal of Organic Chemistry, 2022, 42(2): 434-457.
[2]	Xi Zhao, Yingcong Ou, Yan Liu, Keiji Maruoka, Qian Chen. Recent Progress in the Construction of S—S, P—S and C—S Bonds Involving O₂-Initiated Sulfur-Centered Radicals [J]. Chinese Journal of Organic Chemistry, 2021, 41(9): 3366-3378.
[3]	Xin Wang, Yan Zhang, Kai Sun, Jianping Meng, Bing Zhang. Study on the Application of Photoelectric Technology in the Synthesis of Selenium-Containing Heterocycles [J]. Chinese Journal of Organic Chemistry, 2021, 41(12): 4588-4609.
[4]	Huang Guobao, Li Xiuying, Luo Jinrong, Luo Zhihui, Tan Minxiong. Recent Progress on Synthesis of Sulfur Compounds by Sodium Sulfinates [J]. Chin. J. Org. Chem., 2019, 39(3): 617-624.
[5]	Pan Chengxue, Wang Zhongchang, Su Guifa, Zong Xi, Xue Wenbin, Qin Jiangke. Synthesis, Structure and Properties of Ferrocene-Peptide Conjugates CH3O-Fc-NH-ΔPhe-COPh [J]. Chin. J. Org. Chem., 2012, 32(04): 742-746.
[6]	Chen Guoqiang;Guo Yinlong. Study on the Ion/Molecule Reactions of Low-Mass Compounds in the Ion Trap Mass Spectrometre [J]. Chin. J. Org. Chem., 2003, 23(9): 977-983.
[7]	Li Renyu;Bei Fengli;Wang Jun;Yang Xujie;Xu Xingyou;Lu Lude;Wang Xin. 0108 [J]. Chin. J. Org. Chem., 2003, 23(9): 984-987.
[8]	Lu Jun;Li Yingying;Yang Ling;Bai Yinjuan;Tian Min. Study on the Condensation Reactions between Aromatic Aldehydes and Thiobarbituric Acid [J]. Chin. J. Org. Chem., 2003, 23(9): 958-960.
[9]	Yin Handong;;. Synthesis and Characterization of Drum Organooxotin Cluster [PhCH_2Sn(O)(O_2CCH=CHAr)]_6 and Crystal Structure of [PhCH_2Sn(O) (O_2CCH=CHPh)]_6 [J]. Chin. J. Org. Chem., 2003, 23(9): 961-966.
[10]	Wang Sihong;Zhao Hua;Gao Yongjun. Synthesis and Elucidation of Indoprofen Analogues [J]. Chin. J. Org. Chem., 2003, 23(9): 1022-1025.
[11]	Liu Taiqi;Ding Fuchen;Lin Yonghua;Yu Jianxiang;Shi Qisong;Shen Qi. A Novel Reaction of (CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb) with Cyclopentadiene Forming (C_5H_5)_3Ln·THF [J]. Chin. J. Org. Chem., 2003, 23(9): 1029-1032.
[12]	Han Guangfan;Wang Jinjun;Jiang Guiji. Synthesis of Chroman-4-ono[2,3-b]quinolinone Derivatives [J]. Chin. J. Org. Chem., 2003, 23(9): 1004-1007.
[13]	Xu Xinhua;Huang Rongxin;Lu Ruiliang;Zhang Qiulin. A Simple and Conventient Method for the Synthesis of Allylic Selenides via Reasction of Allylic Zinc with Diaryl Diselenides [J]. Chin. J. Org. Chem., 2003, 23(8): 865-866.
[14]	Dai Liyan;Chen Yingqi. Novel Synthesis of Arylfluoroquinolone Antimicrobial Agents [J]. Chin. J. Org. Chem., 2003, 23(8): 836-840.
[15]	Li Renyu;Bei Fengli;Ma Weixing;Yang Xujie;Xu Xingyou;Lu Lude;Wang Xin. One Step Sysnthesis of N-Salicylidene-4-aminoantipyrine by Solid Phase Reaction at Room Temperature [J]. Chin. J. Org. Chem., 2003, 23(8): 846-849.

含半夹心结构铑的1,1'-二硫(硒、碲)二茂铁化合物

Pentamethylcyclopentadienyl halfsandwich rhodium complexes containing 1,1'- ferrocene dichalcogenido chelate ligands

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments