Synthesis of 1-amino-2-(2'-methyl-4'-methyl propionate)  phenoxy-4- hydroxy anthraquinone

Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (4): 533-536. Previous Articles Next Articles

1-氨基-2-(2'-甲基-4'-丙酸甲酯)苯氧基-4-羟基蒽醌的合成

胡莹玉;李红斌;孙灵;沈永嘉;邱忠成

上海大学环境与建筑工程学院;华东理工大学精细化工研究所;上海分析仪器总厂

发布日期:2000-08-25

Synthesis of 1-amino-2-(2'-methyl-4'-methyl propionate) phenoxy-4- hydroxy anthraquinone

Hu Yingyu;Li Hongbin;Sun Ling;Shen Yongjia;Qiu Zhongcheng

Published:2000-08-25

Abstract

2-Methyl-4-β-cyanoethylphenol was synthesized via Friedel-Crafts reaction between o-cresol and acrylonitrile. It was condensed with 1- amino-2-bromo-4-hydroxy anthraquinone by the nucleophilic reaction. The product was hydrolyzed in alkaline medium and esterified with methanol to afford the title compound. Mass, ^1H NMR, element analyses, Vis spectra and the melting points of the title compound and the intermediates were measured.

Key words: PROPIONATE, PHENOXY GROUP, ANTHRAQUINONE P, PHENOL P, ACRYLONITRILE, MASS SPECTROGRAPHY, PROTON MAGNETIC RESONANCE SPECTROMETRY, ELEMENTAL ANALYSIS

CLC Number:

O621

Cite this article

Hu Yingyu;Li Hongbin;Sun Ling;Shen Yongjia;Qiu Zhongcheng. Synthesis of 1-amino-2-(2'-methyl-4'-methyl propionate) phenoxy-4- hydroxy anthraquinone[J]. Chin. J. Org. Chem., 2000, 20(4): 533-536.

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1-氨基-2-(2'-甲基-4'-丙酸甲酯)苯氧基-4-羟基蒽醌的合成

Synthesis of 1-amino-2-(2'-methyl-4'-methyl propionate) phenoxy-4- hydroxy anthraquinone

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