Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (6): 924-926. Previous Articles     Next Articles

1-甲基-1-乙基-3-丁烯基环戊二烯基稀土二氯化物的 合成与表征

林进;赵汝琪;王昭煜   

  1. 河北师范大学化学系.石家庄(050016)
  • 发布日期:2000-12-25

Syntheses and characterizations of 1-methyl-1-ethyl-3-butenyl cyclopentadienyl lanthanide dichloride complexes

Lin Jin;Zhao Ruqi;Wang Zhaoyu   

  1. Hebei Teachers Univ, Dept Chem.Shijiazhuang(050016)
  • Published:2000-12-25

the trichlorides of lanthanum, neodymium, samarium and gadolinium reacted with an equivalent [C~5H~4C(CH~3)(C~2H~5)CH~2CH=CH~2]MgCl in THF at room temperature for 12 h to give 1-methyl-1-ethyl-3-butenyl cyclopentadienyl lanthanide dichloride complexes. Their constitutional formula were characterized by elementary analyses, MS, IR and ^1H NMR to be [C~5H~4C(CH~3)(C~2H~5)CH~2CH=CH~2]LnCl~2· MgCl~2· THF[Ln=La(1), Nd(2), Sm(3), Gd(4)].

Key words: CYCLOPENTADIENE P, ELEMENTAL ANALYSIS, MASS SPECTROGRAPHY, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, NEODYMIUM COMPLEX, LANTHANUM COMPLEX, SAMARIUM COMPLEX, GADOLINIUM COMPLEX

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