Synthesis of organo-silicon epoxide directly from natural  SiO2 and the product characterization

Chin. J. Org. Chem. ›› 2001, Vol. 21 ›› Issue (1): 53-55. Previous Articles Next Articles

直接由SiO2低温合成含硅环氧化合物及其结构表征

宋建华;刘安华;孙陆逸;龚克成

广州大学桂花岗校区化学系;华南理工大学材料学院高分子结构与改性研究室

发布日期:2001-01-25

Synthesis of organo-silicon epoxide directly from natural SiO2 and the product characterization

Song Jianhua;Liu Anhua;Sun Luyi;Gong Kecheng

Published:2001-01-25

Abstract

A highly reactive pentacoordinate organic silicon complex was prepared by means of reaction of natural silica with ethylene glycol in the presence of potassium hydroxyde. A novel organo- silicon epoxide was synthesized by reaction of epichlorohydrin with the pentacoordinate silicon complex. The product was characterized by FTIR、NMR、TG, EPS, etc.

Key words: SILICON DIOXIDE, SILICA PIGMENT, SILICON COMPLEX, DIRECT REACTIONS, EPOXIDE, PENTACOORDINATE, ORGANO SILICON COMPOUNDS, STRUCTURE CHARACTERISTICS

CLC Number:

O627

Cite this article

Song Jianhua;Liu Anhua;Sun Luyi;Gong Kecheng. Synthesis of organo-silicon epoxide directly from natural SiO2 and the product characterization[J]. Chin. J. Org. Chem., 2001, 21(1): 53-55.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Liangcai Yao, Jinghan Gui. Application of the Radical Polyene Cyclization Reaction in Natural Product Synthesis [J]. Chinese Journal of Organic Chemistry, 2022, 42(9): 2703-2714.
[2]	Qingfeng Du, Lu Zhang, Feng Gao, Le Wang, Wanbin Zhang. Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Epoxides and Aziridines [J]. Chinese Journal of Organic Chemistry, 2022, 42(10): 3240-3262.
[3]	Gucheng Yuan, Jiawei Liu, Shihang Yu, Chaonan Yuan, Qinghua Bian, Min Wang, Jiangchun Zhong. Asymmetric Synthesis of (3Z,6Z,9S,10R)-9,10-Epoxy-3,6-heneicosadiene, Sex Pheromone Component of Hyphantria cunea [J]. Chinese Journal of Organic Chemistry, 2021, 41(11): 4437-4443.
[4]	Liu, Quanyao, Shi, Lei, Liu, Ning. Pyridine Bridged Organocatalyst for the Synthesis of 3-Aryl-2-oxazolidinones from Carbon Dioxide, Terminal Epoxide, and Aryl Amine [J]. Chinese Journal of Organic Chemistry, 2019, 39(10): 2882-2891.
[5]	Sun Yunkai, Zhang Jin, Liu Huijun, Wang Xiaofeng. Synthesis and Polymerization of Optically Active Epoxides with Diazafluorenyl Substituent [J]. Chin. J. Org. Chem., 2018, 38(1): 253-258.
[6]	Nie Shipeng, Shen Wei, Gao Yuhua, Tang Yan, Zhang Xiang, Gu Xiaoyu, Lu Hongfei. Application of (C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂ in the Synthesis ofHydratropic Aldehyde and Its Analogs [J]. Chin. J. Org. Chem., 2015, 35(11): 2393-2398.
[7]	Huang Shaoxu, Wang Yong, Long Yaqiu. Advances in the Research of Human Soluble Epoxide Hydrolase Inhibitors [J]. Chin. J. Org. Chem., 2012, 32(05): 877-888.
[8]	HE Shi-Hua, WANG Chun-Ting. A Vinyl Epoxide Based Approach to 6β,7β-Methylene in Androstanes [J]. Chin. J. Org. Chem., 2011, 31(03): 379-382.
[9]	Wang, Chaoyang; Song, Guangwei ; Zhu, Jintao*. Efficient Kinetic Resolution of Terminal Epoxides with Phthalimide Using Chiral Salen(Co)(OAc) [J]. Chin. J. Org. Chem., 2009, 29(07): 1142-1146.
[10]	Zhang, Wanxuan*; Ye, Kang; Liu, Liqing; Cao, Meng. Alcoholysis of Epoxides and Aziridines Catalyzed by Quaternary Ammonium Bisulfate [J]. Chin. J. Org. Chem., 2009, 29(05): 794-797.
[11]	CAO Jing,LI Ji-Chao,OUYANG Kun-Bing,WANG Pang-Deng,YANG Nian-Fa*. Synthesis of Chirally Pure 4,4-Diphenylsubstituted Termi-nalAlkene Epoxides [J]. Chin. J. Org. Chem., 2008, 28(03): 428-431.
[12]	ZHANG Li-Li,LIU An-Hua*,ZENG Xing-Rong. Synthesis of Caged Bicyclic Phosphorous-Functionalized Silsesquioxane [J]. Chin. J. Org. Chem., 2007, 27(03): 424-427.
[13]	LI Lei,REN Zhong-Jiao*,CAO Wei-Guo,HUANG Pei-Gang,ZHU Hua. Solvent-Free Darzens Condensation Reaction of AromaticAldehydes with Phenacyl Chloride by Grinding [J]. Chin. J. Org. Chem., 2007, 27(01): 120-122.
[14]	WANG Lei,b ,LI Ye-Zhi^a,HUANG Hua-Min^a,FANG Wei-Shuo*^,b. Catalytic Enantioselective Ring Opening of Epoxides [J]. Chin. J. Org. Chem., 2006, 26(9): 1208-1216.
[15]	ZHANG Li-Li,LIU An-Hua*,ZENG Xing-Rong,WEN Yong-Xiang. Synthesis and Characterization of Caged Bicyclic Phosphorous Quadridentate Silicon Complex [J]. Chin. J. Org. Chem., 2006, 26(08): 1125-1129.

直接由SiO2低温合成含硅环氧化合物及其结构表征

Synthesis of organo-silicon epoxide directly from natural SiO2 and the product characterization

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments