Improvements on the synthesis of the minor components  of the aggregation pheromone of the west indian sugarcane  borer

Chin. J. Org. Chem. ›› 2002, Vol. 22 ›› Issue (1): 52-55. Previous Articles Next Articles

西印度蔗螟聚集信息素次要组份合成方法的改进

李焰;田娟;黄锦霞

湖北大学化学与材料科学学院.武汉

发布日期:2002-01-25

Improvements on the synthesis of the minor components of the aggregation pheromone of the west indian sugarcane borer

Li Yan;Tian Juan;Huang Jinxia

Hubei Univ, North-China Univ of Electr Power.Wuhan

Published:2002-01-25

Abstract

Both enantiomers of 2-methyl-4-heptanol and 2-methyl- 4-octanol, the minor components of the aggregatio pheromone produced by th emale and female West Indian sugarcane borer (Metamasius hemipterus), have been synthesized starting from natural product (S)-leucine. The key step is preparation of (2R) and (2S)-4-methyl-1, 2-oxidopentane from (2S)- 4-methyl-entane- 1, 2-diol. The optical purity of the target products is over 95%.

Key words: ENANTIOMORPH, DIATRAEA SACCHARALIS, LEUCINE, OCTANOL P, PHEROMONE, INSECT HORMONE

CLC Number:

O629

Cite this article

Li Yan;Tian Juan;Huang Jinxia. Improvements on the synthesis of the minor components of the aggregation pheromone of the west indian sugarcane borer[J]. Chin. J. Org. Chem., 2002, 22(1): 52-55.

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西印度蔗螟聚集信息素次要组份合成方法的改进

Improvements on the synthesis of the minor components of the aggregation pheromone of the west indian sugarcane borer

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