Synthesis and reaction of a powerful nucleophilic long-chain imidazole-2-aldoxime

Chin. J. Org. Chem. ›› 2002, Vol. 22 ›› Issue (2): 130-134. Previous Articles Next Articles

一种高亲核怀长链咪唑肟的合成与反应

戴秋云;黄启斌;邓云度

北京防化研究院.北京(102205)

发布日期:2002-02-25

Synthesis and reaction of a powerful nucleophilic long-chain imidazole-2-aldoxime

Dai Qiu Yun;Huang Qibin;Deng Yundu

Research Institute of Chemical Defence.Beijing(102205)

Published:2002-02-25

Abstract

A new long-chain oxime N-tetradecylimidazole-2-aldoxime (1) was designed and synthesized. The reactivities of 1 and other long-chain oximes with p-nitrophenyl diphenyl phosphate (PNPDPP), p-nitrophenyl diethyl thiophosphate (parathion), and O-ethyl (s-β- diisopropylaminoethyl) emthyl phosphonothiolate (V_x) were studied. The results showed that 1 was a powerful nucleophile that was 5 ～ 10 times more active than those oximes reported so far and was useful in non-corrosive decontamination of stable and toxic phosphate esters.

Key words: TETRADECYL;GLYOXALINE P;FORMALDEHYDE P;OXIME, NUCLEOPHILIC REACTION

CLC Number:

O621

Cite this article

Dai Qiu Yun;Huang Qibin;Deng Yundu. Synthesis and reaction of a powerful nucleophilic long-chain imidazole-2-aldoxime[J]. Chin. J. Org. Chem., 2002, 22(2): 130-134.

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一种高亲核怀长链咪唑肟的合成与反应

Synthesis and reaction of a powerful nucleophilic long-chain imidazole-2-aldoxime

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