Synthesis, Spectrum Study and Biological Activity of Salicylaldehyde Salicylhydrazone Complexes with Rare Earth

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (12): 1387-1392. Previous Articles Next Articles

水杨醛水杨酰腙及其稀土配合物的合成、波谱研究及生物活性

何水样;陈军利;杨锐;武望亭;赵建社;史启祯;王汝贤

西北大学化学系;西北农林科技大学植保学院

发布日期:2003-12-25

Synthesis, Spectrum Study and Biological Activity of Salicylaldehyde Salicylhydrazone Complexes with Rare Earth

He Shuiyang;Chen Junli;Yang Rui;Wu Wangting;Zhao Jianshe;Wang Ruxian;Wang Ruxian

Department of Chemistry,Northwest University,Shaanxi Key Laboratory of Physico-Inorganic Chemistry;Institute of Plant Protection, Northwest Science and Technology University of Agriculture and Forestry

Published:2003-12-25

Abstract

Salicylaldehyde salicylhydrazone (C_14H_12N_2O_3, H_3L) and its thirteen new complexes with rare earth have been synthesized. The formula of the complexes is K[RE(HL)_2]·nH_2O (RE = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er, Tm, Yb, Lu, Y; HL is the dinegative ion of Salicylaldehyde salicylhydrazone), which can be confirmed by elemental analysis, chemical analysis and molar conductance. The bond formation of the complexes was characterized by IR, ~1H NMR and UV, and the relationship of the emission wavelength with the atomic number and ion force, which coincided with some law was characterized by fluorescence. The bioactivity test shows the different bacteriostasis effects of the complexes against Phytophthora capsic, Fusarium oxysporium f. sp and vasinfoltum, Altemaaria altemaea.

Key words: salicylic aldehyde;HYDRAZONE;LANTHANUM COMPLEX;PRASEODYMIUM COMPLEX, NEODYMIUM COMPLEX;SAMARIUM COMPLEX;EUROPIUM COMPLEX;RARE EARTH METAL COMPLEX, IR;1HNMR;UV

CLC Number:

O621

Cite this article

He Shuiyang;Chen Junli;Yang Rui;Wu Wangting;Zhao Jianshe;Wang Ruxian;Wang Ruxian. Synthesis, Spectrum Study and Biological Activity of Salicylaldehyde Salicylhydrazone Complexes with Rare Earth[J]. Chin. J. Org. Chem., 2003, 23(12): 1387-1392.

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水杨醛水杨酰腙及其稀土配合物的合成、波谱研究及生物活性

Synthesis, Spectrum Study and Biological Activity of Salicylaldehyde Salicylhydrazone Complexes with Rare Earth

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