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Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (3): 286-287. Previous Articles     Next Articles

硒插入C-Zn键及其生成物与环氧

刘文奇;黄荣新;许新华   

  1. 郴州高等师范专科学校化学系;湖南大学化学化工学院
  • 发布日期:2003-03-25

Reaction of Epoxide or aβ-Unsaturated Esters (Nitrites) with Selenium Insertion Adduct of Arylzinc Halides

Liu Wenqi;Huang Rongxin;Xu Xinhua   

  1. Department of Chemistry,Chenshou Teacher College;College of Chemistry and Chemical Engineering,Hunan University
  • Published:2003-03-25

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Aryl zinc selenoates were fonned through selenium insertion into the zinc-carbon bond of aryl zinc halides. Reaction of the insertion adducts with epoxides and a, β-unsaturated esters ( nitriles) in THF- HMPA afforded the corresponding unsymmetrical selenides, respectively.

Key words: ORGANO SELENIUM COMPOUNDS;ZINC COMPOUNDS;EPOXIDE;INSERTION REACTION, ESTERS;ETHER

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